首页|Heterolytic carbon–iodine bond cleavage by a palladium(i) metalloradical
Heterolytic carbon–iodine bond cleavage by a palladium(i) metalloradical
扫码查看
点击上方二维码区域，可以放大扫码查看
原文链接
NSTL
Royal Soc Chemistry
The well-defined Pd(i) metalloradical [Pd(PtBu3)2]+ reacts with aryl and alkyl iodides at room temperature, yielding [Pd(PtBu3)(μ-I)]2 and phosphonium salts. Pd(ii) aryl/alkyl derivates, reflecting net radical oxidative addition of the substrate to the metalloradical, are generated during the reaction and two examples have been isolated and crystallographically characterised.
NSTL
Royal Soc Chemistry
