首页|Macro copper-graphene composites with enhanced electrical conductivity

Macro copper-graphene composites with enhanced electrical conductivity

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  • NSTL
  • Elsevier
Composites demonstrating enhanced electrical conductivity compared to copper have been highly sought after for their advantages in efficient energy transport behavior. While such conductors have been demonstrated in 1D (nanowires) and 2D (films) samples, achieving similar behavior in 3D has been challenging owing to the limitations of the synthesis techniques used. In this paper, novel macro-scale 3D copper conductors were demonstrated with increased electrical conductivity through the addition of graphene. Hot extrusion was used to manufacture 12 AWG copper-graphene composite wires with varying graphene content and defect density. Graphene defect density was measured using Raman spectroscopy. Results showed that the electrical conductivity of composites with low defect density graphene increased as a function of graphene content. Comparatively composites with high defect density graphene demonstrated lower electrical conductivity. This study provides first-of-its-kind evidence of 3D metal composites whose bulk electrical performance has been enhanced using graphene additive in minute quantities (15 ppm). Further developments in this area are essential to achieve high performance composite conductors that can improve energy transport efficiency and pave way for industrial adoption of such materials in the future. (c) 2021 Elsevier B.V. All rights reserved.

CopperConductorGrapheneMetal compositesSolid phase processingExtrusionEnhanced conductivityCarrier scatteringEnergy efficient materialsMATRIX COMPOSITESDYNAMIC RECRYSTALLIZATIONNANOCRYSTALLINE COPPERGRAIN-BOUNDARIESCVDMICROSTRUCTURESTABILIZATIONSTRENGTHQUALITY

Kappagantula, Keerti S.、Smith, Jacob A.、Kraft, Frank F.、Nittala, Aditya K.

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Pacific Northwest Natl Lab

Ohio Univ

2022

10.1016/j.jallcom.2021.162477

Journal of Alloys and Compounds

Journal of Alloys and Compounds

EISCI
ISSN：0925-8388
年,卷(期)：2022.894
  • 12
  • 72