首页|Studies of Ni-Mg catalyst for stable high efficiency hydrogen storage
Studies of Ni-Mg catalyst for stable high efficiency hydrogen storage
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? 2022 Elsevier B.V.Doping engineering is an effective strategy to improve the hydrogen storage capacity of magnesium-based materials. Here, we report a magnesium composite containing trace amounts of nickel catalyst (Ni-Mg), in which Ni and Mg layers form a new structural phase. The test shows that Ni-Mg composite has a hydrogen storage capacity of 7.5 wt%, with rapid absorption/desorption kinetics and stable reversible absorption/desorption performance on cycling. Ni-Mg exhibits a superior hydrogen storage performance as compared to the MgNi alloys and Mg-based materials previously reported in the literature. We conclude that a new MgNi phase and MgNi2 intermetallic compound are formed during the H2 adsorption process. Based on the theoretical calculations, we show that Ni facilitates hydrogenation by accelerating the dissociation of H2 molecules into the H atoms, while the MgNi phase formed during the hydrogenation is conducive to the subsequent dehydrogenation, promoting H atoms diffusion between the subsurface and the surface. This work provides a guidance for the development of the efficient hydrogen storage materials.
Zhang H.、Zong Y.、Xu J.、Xu H.、Liu X.、Luo J.、Liang H.
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Institute of Functional Nano & Soft Materials (FUNSOM) Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices Soochow University
Institute for New Energy Materials & Low-Carbon Technologies and Tianjin Key Lab of Photoelectric Materials & Devices School of Materials Science and Engineering Tianjin University of Technology
Institute of Material and Chemical Engineering Xuzhou University of Technology
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