首页|A selective replacement strategy to a deep-red phosphor for plant growth and optical temperature sensing

A selective replacement strategy to a deep-red phosphor for plant growth and optical temperature sensing

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? 2022For the absorption of plants, it is important to synthesize phosphors with emission bands in the red region. Herein, a series of new red phosphors Sr1-xLa2+xAl2-xO7: xMn4+ (SLA: xMn4+) were synthesized by the high temperature solid-state reaction. The inconsistent charge number of Mn4+ dopant and substituted Al3+ ion can be compensated by manual adjusting of the proportion of Sr2+ and La3+ in the same crystallography site. The phosphor shows emission band at around 713 nm, which fits well with the absorption of Pfr (far-red light-absorbing phytochrome), meaning that the SLA: 0.006Mn4+ can promote plant growth. Furthermore, co-doped phosphor SLA: 0.006Mn4+, 0.006Dy3+ was prepared with interesting temperature-dependent luminescence. With temperature increasing, the emitting intensity of Mn4+ has a more pronounced decline in comparison with Dy3+. Due to this feature, SLA: 0.006Mn4+, 0.006Dy3+ can be used as a non-contact optical thermometer with Sa of 0.018 K?1 at 450 K and Sr of 1.458% K?1 at 425 K.

Optical temperature sensingPhosphorPhotoluminescencePlant growth

Liu W.、Zhao D.、Zhang R.-J.、Fan Y.-P.、Zhu S.-Y.、Yao Q.-X.

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College of Chemistry and Chemical Engineering Henan Polytechnic University

School of Chemistry and Chemical Engineering Shandong Provincial Key Laboratory/Collaborative Innovation Center of Chemical Energy Storage and Novel Cell Technology Liaocheng University

2022

Journal of Alloys and Compounds

Journal of Alloys and Compounds

EISCI
ISSN:0925-8388
年,卷(期):2022.924
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