首页|Photoredox Catalyzed Sulfonylation of Multisubstituted Allenes with Ru(bpy)(3)Cl-2 or Rhodamine B
Photoredox Catalyzed Sulfonylation of Multisubstituted Allenes with Ru(bpy)(3)Cl-2 or Rhodamine B
扫码查看
点击上方二维码区域，可以放大扫码查看
原文链接
NSTL
Elsevier
A highly regio- and stereoselective sulfonylation of allenes was developed that provided direct access to alpha, beta-substituted unsaturated sulfone. By means of visible-light photoredox catalysis, the free radicals produced by p-toluenesulfonic acid reacted with multisubstituted allenes to obtain Markovnikov-type vinyl sulfones with Ru(bpy)(3)Cl-2 or Rhodamine B as photocatalyst. The yield of this reaction could reach up to 91%. A series of unsaturated sulfones would be used for further transformation to some valuable compounds. (C) 2021 Elsevier B.V. All rights reserved.
NSTL
Elsevier
