Journal of Alloys and Compounds2022,Vol.90812.DOI:10.1016/j.jallcom.2022.164447

A novel hybridized needle-like Co3O4/N-CNO composite for superior energy storage asymmetric supercapacitors

Pallavolu M.R. Nallapureddy R.R. Joo S.W. Kumar Y.A. Mani G. Albaqami M.D. Karami A.M. Parvathala A.
Journal of Alloys and Compounds2022,Vol.90812.DOI:10.1016/j.jallcom.2022.164447

A novel hybridized needle-like Co3O4/N-CNO composite for superior energy storage asymmetric supercapacitors

Pallavolu M.R. 1Nallapureddy R.R. 1Joo S.W. 1Kumar Y.A. 2Mani G. 3Albaqami M.D. 3Karami A.M. 3Parvathala A.4
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作者信息

  • 1. School of Mechanical Engineering Yeungnam University
  • 2. Department of Materials Science and Engineering Seoul National University of Science and Technology
  • 3. Department of Chemistry College of Science King Saud University
  • 4. Department of Physics Sri Venkateswara University
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Abstract

? 2022 Elsevier B.V.The controlled growth of needle-like Co3O4 and composite formation with highly graphitic carbons such as N-CNOs is critically essential for obtaining high-performance energy storage supercapacitors. In this study, the needle-like Co3O4 and graphitic N-CNOs are synthesized by the simple solvothermal and pyrolysis methods, respectively. The Co3O4/N-CNO composite enhances the fast charge transfer by reducing ion diffusion. The Co3O4/N-CNO composite demonstrated an improved specific capacitance (3066 F g?1) than the needle-like structure of Co3O4 (2068 F g?1). The Co3O4/N-CNO composite exhibited very good rate capability and high capacitance retention of 82% at a high current density of 8 A g?1 meanwhile the Co3O4/N-CNO//AC ASC device shows high power and energy densities with capacitance retention of 78% and Coulombic efficiency of 100% over 2000 cycles. This attractive electrochemical performance of Co3O4/N-CNO composite makes it a favorable device for practical applications of supercapacitors.

Key words

Asymmetric supercapacitors/Co3O4/N-CNO composite/Needle-like structure/Pyrolysis/Solvothermal

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出版年

2022
Journal of Alloys and Compounds

Journal of Alloys and Compounds

EISCI
ISSN:0925-8388
被引量11
参考文献量61
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