首页|Bis(Cyclic Alkyl Amino Carbene) Ruthenium Complexes: AVersatile, Highly Efficient Tool for Olefin Metathesis

Bis(Cyclic Alkyl Amino Carbene) Ruthenium Complexes: AVersatile, Highly Efficient Tool for Olefin Metathesis

扫码查看
原文链接
  • NSTL
  • Wiley
The state-of-the-art in olefin metathesis is application of N-heterocyclic carbene (NHC)-containing ruthenium alkylidenes for the formation of internal C=C bonds and of cyclic alkyl amino carbene (CAAC)-containing ruthenium benzylidenes in the production of terminal olefins. A straightforward synthesis of bis(CAAC) Ru indenylidene complexes, which are highly effective in the formation of both terminal and internal C=C bonds at loadings as low as 1 ppm, is now reported.

carbenesethenolysisindenylidenesolefin metathesisruthenium

Gawin, Rafal、Kozakiewicz, Anna、Gunka, Piotr A.、Skowerski, Krzysztof、Dabrowski, Pawel

展开 >

Apeiron Synth SA, Dunska 9, PL-54427 Wroclaw, Poland

Univ Nicolaus Copernicus Torun, Fac Chem, Gagarina 7, PL-87100 Trorun, Poland

Warsaw Univ Technol, Fac Chem, Noakowskiego 3, PL-00664 Warsaw, Poland

Wroclaw Univ Sci & Technol, Fac Chem, Wybrzeze Wyspianskiego 27, PL-50370 Wroclaw, Poland

展开 >

2017

10.1002/anie.201609009

Angewandte Chemie

Angewandte Chemie

ISSN：1433-7851
年,卷(期)：2017.56(4)
  • 68
  • 82