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Sulfidation failure of UMCo-50 protective sheath tube used for a temperature monitoring device exposed to sulfur dioxide bearing hot gas

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? 2022 Elsevier LtdThe failure investigation of a thermocouple protective sheath tube made of UMCo-50 cobalt base alloy exposed to SO2-bearing hot gas in a sulfur refining furnace was systematically conducted. Various microstructural examination techniques were employed in order to clarify a root cause of failure. A tip portion of protective sheath tube remarkably revealed its severe material degradation after exposure to SO2-bearing hot gas in service for approximately 6 months. From the investigation, it turned out that the alloy was significantly prone to sulfidation attacks due to the formation of undesired chromium-rich carbides in its structure, which was accelerated by temperature fluctuation between 550 and 1100 °C during service. As a result, the protective sheath tube could not last for approximately 3 years as its design life.

Chromium-rich carbidesSO2-bearing hot gasSulfidation attacksUMCo-50 cobalt base alloy

Ouampan S.、Kaewkumsai S.、Viyanit E.

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National Science and Technology Development Agency (NSTDA)

2022

Engineering failure analysis

Engineering failure analysis

EISCI
ISSN:1350-6307
年,卷(期):2022.138
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