Abstract
? 2022Samarium-cobalt (Sm-Co) sintered magnets have high magnetic energy densities, great resistance to demagnetization and corrosion, and excellent thermal stability in a wide temperature range (–50–550 °C). However, the utilization of these magnets is restricted by their brittleness. Based on micromechanical and the Zener pinning model, Sm-Co sintered magnets with improved mechanical properties have been designed and fabricated via microstructure engineering. A small amount of fine Sm2O3 particulates (0–3 wt%) has been incorporated into Sm2(CoFeCuZr)17 sintered magnets to refine the grain size by up to approximately 50% (from 45 to 22 μm) and narrow the grain size distribution. Doping with 3 wt% Sm2O3 increased the flexural strength by 62% while maintaining magnetic performance. Both grain-refined unimodal microstructure and heterogeneous laminated coarse/fine grain microstructure were formed by strategically designed assemblies of Sm2O3-added Sm-Co powder feedstock mixtures. The technology is compatible with existing magnet manufacturing processes. Numerical micromechanics simulation indicates that the fracture is dominated by intragranular mode. The mechanical strength is mainly enhanced by the additive-induced grain refinement, while the small amount of Sm2O3 addition has a small direct positive contribution. These magnets will be more cost-effective, efficient, and robust for various functional applications.
NSTL
Elsevier