首页|Electrodeposition of silane/reduced graphene oxide nanocomposite on AA2024-T3 alloy with enhanced corrosion protection, chemical and mechanical stability

Electrodeposition of silane/reduced graphene oxide nanocomposite on AA2024-T3 alloy with enhanced corrosion protection, chemical and mechanical stability

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? 2022 Elsevier B.V.Hydrophobic silane/reduced graphene oxide (rGO) nanocomposites were successfully constructed on an AA2024-T3 aluminum alloy surface using a facile co-electrodeposition process. The composition and morphology were characterized by ATR-FTIR, XRD, Raman spectroscopy, EDX, XPS and SEM. The results revealed that the implanted GO nanosheets were partially reduced and successfully covalently bonded with silanol groups to fabricate a more compact and denser coating. Electrochemical measurements demonstrated that the electrodeposited silane/rGO nanocomposite markedly decreased the corrosion rate of the AA2024-T3 alloy in 3.5 wt% NaCl solution. The protection efficiency was maintained over 96% after 120 h of exposure, presenting excellent chemical stability. Meanwhile, a sand paper abrasion test was performed to evaluate the mechanical robustness and the contact angle was reduced by only 4.5° after 150 abrasion cycles. The excellent anti-corrosion property and mechanical robustness, along with the feasible electrodeposition procedure, show its great potential for industrial applications.

AA2024-T3 aluminum alloyCorrosion protectionElectrodepositionGraphene oxide

Zhang H.H.、Liu Y.W.、Bian H.、Zhang Y.、Yang Z.N.、Zhang Z.、Chen Y.

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Department of Chemical Engineering and Safety Binzhou University

Department of Chemistry Zhejiang University

School of Materials Science and Hydrogen Energy Foshan University

2022

Journal of Alloys and Compounds

Journal of Alloys and Compounds

EISCI
ISSN:0925-8388
年,卷(期):2022.911
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