Molecules2019,Vol.24Issue(24) :21.DOI:10.3390/molecules24244605

Extraction of Metal Ions with Metal-Organic Frameworks

Natalia Manousi Dimitrios A.Giannakoudakis Erwin Rosenberg
Molecules2019,Vol.24Issue(24) :21.DOI:10.3390/molecules24244605

Extraction of Metal Ions with Metal-Organic Frameworks

Natalia Manousi 1Dimitrios A.Giannakoudakis 2Erwin Rosenberg3
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作者信息

  • 1. Laboratory of Analytical Chemistry,Department of Chemistry,Aristotle University of Thessaloniki,54124 Thessaloniki,Greece
  • 2. Institute of Physical Chemistry,Polish Academy of Sciences,Kasprzaka 44/52,01-224 Warsaw,Poland
  • 3. Institute of Chemical Technology and Analytics,Vienna University of Technology,1060 Vienna,Austria
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Abstract

Metal-organic frameworks(MOFs)are crystalline porous materials composed of metal ions or clusters coordinated with organic linkers.Due to their extraordinary properties such as high porosity with homogeneous and tunable in size pores/cages,as well as high thermal and chemical stability,MOFs have gained attention in diverse analytical applications.MOFs have been coupled with a wide variety of extraction techniques including solid-phase extraction(SPE),dispersive solid-phase extraction(d-SPE),and magnetic solid-phase extraction(MSPE)for the extraction and preconcentration of metal ions from complex matrices.The low concentration levels of metal ions in real samples including food samples,environmental samples,and biological samples,as well as the increased number of potentially interfering ions,make the determination of trace levels of metal ions still challenging.A wide variety of MOF materials have been employed for the extraction of metals from sample matrices prior to their determination with spectrometric techniques.

Key words

MOFs/metals/extraction/sample preparation/microextraction/spectrometry/environmental samples/food samples/biological samples

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出版年

2019
Molecules

Molecules

ISTP
ISSN:1420-3049
被引量23
参考文献量105
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