Applied Catalysis2022，Vol.31213.DOI:10.1016/j.apcatb.2022.121376

In situ investigation of the CO2 methanation on carbon/ceria-supported Ni catalysts using modulation-excitation DRIFTS

Gonsalves, Liliana P. L. Mielby, Jerrik Soares, O. Salome G. P. Sousa, Juliana P. S. Petrovykh, Dmitri Y. Lebedev, Oleg I. Pereira, M. Fernando R. Kegnaes, Soren V. Kolen'ko, Yury
Applied Catalysis2022，Vol.31213.DOI:10.1016/j.apcatb.2022.121376
✕
  • NSTL
  • Elsevier

In situ investigation of the CO2 methanation on carbon/ceria-supported Ni catalysts using modulation-excitation DRIFTS

Gonsalves, Liliana P. L. 1Mielby, Jerrik 2Soares, O. Salome G. P. 3Sousa, Juliana P. S. 1Petrovykh, Dmitri Y. 1Lebedev, Oleg I. 4Pereira, M. Fernando R. 3Kegnaes, Soren 2V. Kolen'ko, Yury1
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作者信息

  • 1. Int Iberian Nanotechnol Lab
  • 2. Tech Univ Denmark
  • 3. Univ Porto
  • 4. Lab CRISMAT
  • 折叠

Abstract

The development of novel cost-efficient, high-performing catalysts for CO2 methanation that are active at low temperatures can be optimized through the understanding of the reaction mechanism on different materials. A series of Ni-based catalysts supported on CeO2 and carbon/CeO2 composites was investigated, showing that Ni nanoparticles supported on a carbon/CeO2 composite with a 50:50 wt ratio and on pure CeO2 have excellent lowtemperature activity and achieve up to 87% CO2 conversion with full selectivity towards CH4 at 370 degrees C. Importantly, meaningful insights on the reaction mechanism were gathered for the different types of materials by using the emerging ME-PSD-DRIFTS technique. The study of the rate of formation/consumption of the various intermediates showed that the CO2 methanation reaction follows a combination of the CO and formate pathways in the case of Ni on pure CeO2; however, in the case of Ni on the carbon/CeO2 composite, it follows only the formate pathway.

Key words

Heterogeneous catalysis/Carbon dioxide/Methane/Reaction mechanism/In situ DRIFTS/DIOXIDE/OXIDE/SPECTROSCOPY/HYDROGENATION/PERFORMANCE/EFFICIENT/METAL/STATE

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出版年

2022
Applied Catalysis

Applied Catalysis

ISSN：0926-3373
被引量16
参考文献量46
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