Journal of Alloys and Compounds2022,Vol.89614.DOI:10.1016/j.jallcom.2021.163025

(163025)A synchrotron X-ray topography study of crystallographic defects in ScAlMgO_4 single crystals

Yongzhao Yao Keiichi Hirano Hirotaka Yamaguchi
Journal of Alloys and Compounds2022,Vol.89614.DOI:10.1016/j.jallcom.2021.163025

(163025)A synchrotron X-ray topography study of crystallographic defects in ScAlMgO_4 single crystals

Yongzhao Yao 1Keiichi Hirano 2Hirotaka Yamaguchi3
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作者信息

  • 1. Japan Fine Ceramics Center, 2-4-1 Mutsuno, Atsuta, Nagoya 456-8587, Japan
  • 2. High Energy Accelerator Research Organization (KEK), 1-1 Oho, Tsukuba 305-0801, Japan
  • 3. Advanced Power Electronics Research Center, National Institute of Advanced Industrial Science and Technology, 1-1-1 Umezono, Tsukuba 305-8568, Japan
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Abstract

ScAlMgO_4 is a promising material that can be used to fabricate lattice-matched substrates for the epitaxial growth of GaN and InGaN. To improve its crystal quality, we used synchrotron X-ray topography to study the dislocations in a 50.8-mm-diameter ScAUvlgO_4 single crystal grown via the Czochralski method. Dislocation character was analyzed in terms of Burgers vectors by comparing dislocation contrasts recorded using sixg-vectors that represented the m+c, a+c, and c-type crystal planes. The central area of the substrate, which corresponded to the portion grown vertically under the seed crystal, was characterized by millimeter-sized domains bound by mixed-type dislocation arrays with both in-plane and c-axis Burgers vectors. Basal plane dislocations (BPDs) typically formed an arrow-like shape with three branches. Growth striations with alternating high- and low-dislocation-density areas were observed in the diameter-expanding area and high-dislocation-density areas were covered with tangled BPD networks. The mechanisms of dislocation generation, multiplication, and reaction are discussed based on their line directions and dislocation character.

Key words

Inorganic material/Oxide material/Crystal growth/Dislocation and disclination/Domain structure/X-ray diffraction

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出版年

2022
Journal of Alloys and Compounds

Journal of Alloys and Compounds

EISCI
ISSN:0925-8388
被引量2
参考文献量45
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