In recent years, molybdenum disulfide (MoS_2) with sandwich structure has been widely studied as cathode material of aqueous rechargeable zinc-ion batteries (ARZIBs), but inherent low capacity and short cycle life limit its further development. Here, we synthesized a novel hydrophilic spherical 1T-MoS_2 through hexadecyl trimethyl ammonium bromide (CTAB) template-assisted hydrothermal reaction as cathode materials for ARZIBs and systematically study its mechanism of electrochemical enhancement. The results suggest that stable spherical MoS_2 was prepared by in-situ reduction of molybdate ion under the electrostatic absorption of CTAB template and 0 element introduced by ethylene glycol (oil-phase solvent) not only increases the hydrophilicity of the material and facilitates the intercalation of ammonium ions and water molecules, but also promotes the formation of the 1 T phase by changing the electronic structure. Consequently, this modified electrode exhibits a reversible capacity of 110 mAh g~(-1) at the current density of 1.0 A g~(-1), and the capacity retention rate is up to 90% after 500 cycles, showing excellent cycling stability and rate performance.
Molybdenum disulfideTemplate-assistedOxygen introductionHydrophilicity1 T phase
Pengfei Cao、Ni Chen、Wenjing Tang
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School of Packaging and Materials Engineering, Hunan University of Technology, Zhuzhou 412007, People's Republic of China
NSTL
Elsevier
