首页|Re-examination of martensitic stabilization in Cu-based shape memory alloys Part I. Identification of occurrence stage and degree of martensitic stabilization in CuZnAl alloys
Re-examination of martensitic stabilization in Cu-based shape memory alloys Part I. Identification of occurrence stage and degree of martensitic stabilization in CuZnAl alloys
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Elsevier
? 2022 Elsevier B.V.Previous work did not identify occurrence stage and degree of martensitic stabilization in Cu-based shape memory alloys due to lower heating rate. By flash heating into liquid metals, we systematically clarified contribution of static ageing and the ones of dynamic ageing during process of quenching and heating to the martensitic stabilization in directly-quenched CuZnAl alloys. We discovered that the dynamic ageing during the cooling process of quenching could instantaneously stabilize a few already formed martensites totally although it did not stabilize the overwhelming majority of martensites. The dynamic ageing during the process of subsequent slow heating was responsible for the partial and total stabilization of overwhelming majority of martensites. Both the amounts of martensites stabilized totally by the two dynamic ageing positively depended on Ms temperature. The conventional up-quenching into oil or air actually made more martensites stabilized due to the dynamic ageing during the process of slow heating. The increase in As temperature owing to the static ageing also positively depended on the Ms temperature. These dependences cannot be explained by two well-known mechanisms for the martensitic stabilization.