首页|Characterization of structural and electrical properties of Ca0.61Nd0.26TiO3 ceramic tailored by complex ions (Al0.5Nb0.5)4+
Characterization of structural and electrical properties of Ca0.61Nd0.26TiO3 ceramic tailored by complex ions (Al0.5Nb0.5)4+
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NSTL
Elsevier
Miniaturization and low power dissipation are a trend for the development of ceramic-based microwave devices. Therefore, the decrease of the dielectric loss properties of microwave dielectric ceramic material compounds with a high dielectric constant is considered a quite important subject. In this work, the Ca0.61Nd0.26TiO3 material configuration with orthorhombic perovskite structure was thoroughly investigated by applying the strategy of (Al0.5Nb0.5)4+ substitution at the B-site. More specifically, the Ca0.61Nd0.26Ti1-x(Al0.5Nb0.5)xO3 sample with a nearly 60% increase in the quality factor (Q×f) was obtained. Also, the relationship between the structural and the electrical properties of Ca0.61Nd0.26Ti1-x(Al0.5Nb0.5)xO3 (0 ≤ x ≤ 0.15) samples were explored via performing X‐ray diffraction (XRD) measurements, Raman spectra, transmission electron microscopy (TEM) and calculation of the insulation resistance, etc. The extracted outcomes divulged that samples at x = 0–0.12 formed a single perovskite-structured phase, while the grain size of samples decreased by increasing the x value, leading to a drop decline of both the dielectric constant (εr) and electrical conductivity. Additionally, insights from the acquired Raman spectra confirmed that the stressed-rigid oxygen octahedral networks could lower the positive τf value of Ca0.61Nd0.26TiO3-based ceramic compounds. Interestingly, as the doping content of (Al0.5Nb0.5)4+ increased, the Ti3+ in samples was restrained at x = 0.04, whereas the insulation properties of the samples increased. Hence, the conductivity loss was declined. Furthermore, the TEM images illustrated the appearance of a 1: 1 ordered structure at the B-site of the (Al0.5Nb0.5)4+-doped samples. As a result, the Q×f value of the samples raised from 11,095GHz at x = 0–17,802 GHz at x = 0.12, enhanced by 60%. On top of that, for the sample with x = 0.15, the existence of the Ca2Nb2O7 phase deteriorated the microwave dielectric properties of the Ca0.61Nd0.26Ti1-x(Al0.5Nb0.5)xO3 samples, and especially Q×f value.
NSTL
Elsevier
