Abstract
The optical properties of thin films of intermetallic Au3Hf were experimentally investigated for the first time, which display significant negative epsilon' in the visible and near infrared regions, hence are clearly plasmonic materials. In contrast to similar alloys, such as films of Au3Zr, the films express more negative epsilon' values and lower epsilon '' values across most of the wavelengths (370-1570 nm) investigated. The Au3Hf films were fabricated by DC magnetron sputtering at a range of deposition temperatures, from room temperature to 415 degrees C, and annealed at different vacuum levels. The films mostly formed as a combination of Au3Hf, Au2Hf and Au4Hf phases when deposited below 400 degrees C, and exclusively Au3Hf phase at above 400 degrees C, indicating key conditions for isolating this phase. The films were stable when annealed at 10(-8) Torr, but when annealed again at 10(-6) Torr the films oxidised and changed into a mix of Au-Hf phases, suggesting resistance to oxidization may be an issue for unencapsulated applications at elevated temperatures. (C) 2022 Published by Elsevier B.V.
NSTL
Elsevier