首页|Heteromolecular H -bond interaction forces and dielectric parameters: Time domain reflectometry studies
Heteromolecular H -bond interaction forces and dielectric parameters: Time domain reflectometry studies
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NSTL
Elsevier
H - bond interactions between acetonitrile(AN)/dimethyl sulfoxide(DMSO) and acetylacetone (AcAc) have been investigated using time domain reflectometry studies. The relaxation time values confirm that 1:1 complex has been formed between AN/DMSO and AcAc, and both the keto and enol forms of AcAc exist as monomers. Antiparallel and parallel alignment of AN/DMSO - AcAc H - bonded dipoles in AN/DMSO and AcAc rich solutions, respectively, have been identified. The g(f) values indicate that non-classical H - bond interactions are operative in AN/DMSO - AcAc solutions. The epsilon(E) vs phi(2) suffers quantitatively a large change from the epsilon(E) vs X-2 plot but, they qualitatively agree each other.
H - bondDielectric relaxationExcess dielectric constantDIMETHYL-SULFOXIDEBINARY-MIXTURESHETEROGENEOUS INTERACTIONINTERMOLECULAR FORCESMOLECULAR INTERACTIONHYDROGEN-BONDSSOLUTIONS FTIRACETONITRILELIQUIDBEHAVIOR
Dineshkumar, P.、Sahana, R.、Shanmugam, R.、Elangovan, A.、Sankaranarayanan, R. K.、Joshi, Y. S.、Arivazhagan, G.、Kumbharkhane, C.
NSTL
Elsevier
