首页|Ternary Vss-V3Si-V5SiB2 eutectic formation in the V-Si-B system

Ternary Vss-V3Si-V5SiB2 eutectic formation in the V-Si-B system

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The solidification behavior close to the ternary Vss-V3Si-V5SiB2 eutectic reaction in the V-Si-B system has been experimentally investigated via arc-melting. According to the microstructure investigation, which is performed by SEM observations, EDS and EBSD measurements and XRD analysis, the composition of the ternary eutectic reaction has been determined at V-9Si-6.5B (at%). Its microstructures in two different sample sections with different cooling rates were further investigated and compared with the calculated result of the developed eutectic growth theory based on the Jackson-Hunt model to reveal the competitive solidification behavior between the two-phase Vss-V5SiB2 and three-phase Vss-V3Si-V5SiB2 eutectic growth. As a result, the liquidus projection around the ternary eutectic reaction was modified and the cross section of the ternary Vss-V3Si-V5SiB2 eutectic coupled zone along the monovariant Vss-V5SiB2 and V3Si-V5SiB2 reaction lines was schematically proposed.

High-temperature alloysIntermetallicsMetallographyMicrostructureScanning electron microscopySEMX-ray diffraction

Schwaiger R.、Hasemann G.、Kruger M.、Yazlak M.、Gorr B.、Yang W.G.

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Forschungszentrum Jülich GmbH Institute of Energy and Climate Research Microstructure and Properties of Materials (IEK-2)

Otto-von-Guericke University Magdeburg Institute of Materials and Joining Technology

University Siegen Institute of Materials Technology

Karlsruhe Institute of Technology Institute for Applied Materials – Applied Materials Physics (IAM-AWP)

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2022

Journal of Alloys and Compounds

Journal of Alloys and Compounds

EISCI
ISSN:0925-8388
年,卷(期):2022.902
  • 38