首页|(162809)A novel low-loss (l-x)(Ca_(0.8)Sr_(0.2))TiO_3-xSmAlO_3 microwave dielectric ceramics with near-zero temperature coefficient

(162809)A novel low-loss (l-x)(Ca_(0.8)Sr_(0.2))TiO_3-xSmAlO_3 microwave dielectric ceramics with near-zero temperature coefficient

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(l-x)Ca_(0.8)Sr_(0.2)TiO_3-xSmAlO_3 (abbreviated as (l-x)CST-xSA) perovskite ceramics were synthesized through the conventional solid-state reaction process. The effects of SmAlO_3 on the microstructure, low-frequency dielectric performances, and microwave dielectric properties for (l-x)CST-xSA ceramics were investigated systematically. All compositions exhibited an orthorhombic perovskite structure with dense surface morphology. With increasing the content of SmAlO_3) the order of B-site cation revealed a trend of increase first and then slowly decreased. The presence of oxygen vacancies in the (l-x)CST-xSA ceramics was detected by using x-ray photoelectron spectroscopy. Excellent temperature stability of dielectric permittivity and low dielectric loss (tan<5 lower than 0.005) were observed for (l-x)CST-xSA ceramics at low frequencies. For x = 0.35 composition, the temperature coefficient of the resonant frequency approached zero. In addition, the dielectric permittivity of 42.0, the quality factor of 39,120 GHz, and the temperature coefficient of resonant frequency of - 6.4 ppm/°C were obtained for 0.65CST-0.35SA ceramics. It is suggested that (l-x)CST-xSA ceramics can be used as a candidate material for various microwave communication components.

Ca_(0.8)Sr_(0.2)TiO_3-SmAlO_3Perovskite ceramicsTemperature-stableLow dielectric lossMicrowave dielectric properties

Ao Zhang、Huiqing Fan、Dingwei Hou

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State Key Laboratory of Solidification Processing, School of Materials Science and Engineering, Northwestern Poly technical University, Xi'an 710072, China

2022

Journal of Alloys and Compounds

Journal of Alloys and Compounds

EISCI
ISSN:0925-8388
年,卷(期):2022.898
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