首页|Anthracite-based reduced graphene oxide/antimony composites as anode materials for high performance sodium ion batteries
Anthracite-based reduced graphene oxide/antimony composites as anode materials for high performance sodium ion batteries
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NSTL
Elsevier
? 2022 Elsevier B.V.As a viable alternative to lithium-ion batteries (LIBs), sodium ion batteries (SIBs) have attracted much more attentions. Herein, anthracite-based reduced graphene oxide/antimony (ARGO/SbX) composites have been successfully prepared as high performance anodes for SIBs. The anode composites have been synthesized by in situ reduction of Sb3+ provided by SbCl3 into Sb particles anchored onto the ARGO surface with the aid of NaBH4 and followed by annealing at 550 ℃ for 2 h. As designed, ARGO/SbX based SIBs can display high specific capacity, superior rate capability (527 mAh g?1 at 0.03 A g?1, 117 mAh g?1 at 10 A g?1), and good cycling stability (77 % of the initial capacity after 1000 cycles at 1 A g?1). The present research provides one low cost and high performance coal-based carbon anodes, which are supposed to accelerate the development of SIBs toward future large-scale applications.
AnthraciteAntimonyReduced graphene oxideSodium ion batteries
Jiang Z.、Zhao Y.、Kang W.、Xing B.、Huang G.、Zhang C.、Jiang H.、Cao Y.
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Henan Key Laboratory of Coal Green Conversion College of Chemistry and Chemical Engineering Henan Polytechnic University
Shangyuquan Coal Mine Guoshen Group Corporation CHN ENERGY
Henan Province Industrial Technology Research Institute of Resources and Materials Zhengzhou University