首页|Fabrication of Co(PO3)(2)@NPC/MoS2 heterostructures for enhanced electrocatalytic hydrogen evolution

Fabrication of Co(PO3)(2)@NPC/MoS2 heterostructures for enhanced electrocatalytic hydrogen evolution

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The development of efficient, inexpensive, and stable hydrogen evolution reaction (HER) electrocatalysts is the key to large-scale water electrolysis technologies for hydrogen production. Constructing heterojunction electrocatalysts has become one of the effective strategies for designing high-performance HER electrocatalysts due to their unique heterogeneous interfaces. Herein, a new strategy of PH3 assisted synthesis of metaphosphate is reported, which is used to construct Co(PO3)2@NPC/MoS2 heterostructures (where NPC is N-doped porous carbon). The results show that the formation of Co(PO3)2@NPC/MoS2 heterogeneous interfaces can optimize the electronic structure of the electrocatalyst and greatly improve its HER performance. As a result, a lower overpotential of 119 mV at 10 mA cm-2 is obtained in alkaline electrolyte. This work provides a new perspective for the design of high-performance electrocatalysts for electrocatalytic water splitting. (c) 2021 Elsevier B.V. All rights reserved.

Cobalt metaphosphateElectrocatalysisHeterostructureHydrogen evolution reaction (HER)MoS2HIGH-PERFORMANCE SUPERCAPACITORSMULTIFUNCTIONAL MATERIALHIGHLY EFFICIENTNANOSHEETSCATALYSTSDESIGNPH

Zheng, Hang -bo、Li, Yu-ling、Wang, Yuan-li、Ma, Feng、Gao, Peng-zhao、Guo, Wen-ming、Qin, Hang、Liu, Xiao-pan、Xiao, Han-ning

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Hunan Univ

Hunan Zhongtai Special Equipments Co Ltd

2022

Journal of Alloys and Compounds

Journal of Alloys and Compounds

EISCI
ISSN:0925-8388
年,卷(期):2022.894
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