Hierarchical metal-organic framework (MOF) pore engineering

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NSTL
Elsevier

外文摘要：Metal-Organic Framework (MOF) is a type of coordination networks with high surface area and tunable chemistry. MOFs are utilized for molecular recognition-related applications. The interaction of MOFs with molecules of interest occurs at the internal and external surfaces of MOFs, where internal surfaces are mostly inside the MOF pores. It is important to tune this interaction by pore engineering. We reviewed pore engineering at 4 different length scales: unit cell, multi-unit cells, mesoscale and macroscale. Additionally, we also discussed practical consequences of pore engineering on mass transfer, heat transfer and mechanical stability of MOF materials.

外文关键词：

Metal-organic frameworksHierarchicalPore engineeringZEOLITIC IMIDAZOLATE FRAMEWORKSIMPROVED HYDROGEN STORAGECORE-SHELLCOORDINATION POLYMERSCATALYTIC PERFORMANCEMECHANICAL-PROPERTIESPOSTSYNTHETIC LIGANDTHERMAL-CONDUCTIVITYELECTRODE MATERIALSRATIONAL SYNTHESIS

作者：

Yin, Xinyang、Alsuwaidi, Ahmad、Zhang, Xueyi

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作者单位：

Penn State Univ

出版年：

2022

DOI：

10.1016/j.micromeso.2021.111633

Microporous and mesoporous materials

EISCI

ISSN：1387-1811

年,卷(期)：2022.330

被引量23
参考文献量211