首页|A novel red emitting NaBa12B7O21F4:xEu(3+)phosphor: Synthesis, structure and luminescence properties
A novel red emitting NaBa12B7O21F4:xEu(3+)phosphor: Synthesis, structure and luminescence properties
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NSTL
Elsevier
NaBa12B7O21F4:xEu(3+) phosphors, where 0 < x <= 0.16, were obtained through the high temperature solid phase reaction method. The phosphors showed significant red fluorescence emission resulting from the dominant D-5(0)-> F-7(2) transitions. The optimum doping concentration of Eu3+ ions in the NaBa(12)B(7)O(21)F(4 & nbsp;)matrix were estimated to be 14 mol%. The phenomenon of concentration quenching was researched, and the concentration quenching of NaBa12B7O21F4:xEu(3+) phosphors maybe caused by the exchanging interaction of Eu3+ ions. Moreover, it was found that the optimal-component NaBa12B7O21F4:xEu(3+) phosphor showed high absolute luminescence quantum efficiency and had a millisecond fluorescence lifetime.
LuminescenceEu < sup > 3+<sup >Red emissionNaBa < sub > 12 <sub > B < sub > 7 <sub > O < sub > 21 <sub > F < sub > 4 <sub >:xEu < sup > 3+<sup >PHOTOLUMINESCENCE PROPERTIESENERGY-TRANSFERPHOSPHORLIGHTEFFICIENCY