Merging gold catalysis and haloethynyl frames: Emphasis on halide-shift processes
Fernandez-Canelas, Paula 1Barrio, Pablo 1Gonzalez, Jose M.1
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作者信息
1. Univ Oviedo
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Abstract
Haloalkynes can enter a wide variety of metal-catalyzed transformation giving rise to the formation of products with or without showing halide-shift. This article offers an overall view of the reactivity of these substrates under gold catalysis. Particular attention is devoted to intramolecular reactions that involve a concomitant halide-shift process for the case of alkynyl iodides as starting materials.(c) 2022 The Author(s). Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
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Elsevier