Synthesis and electroluminescent property of aluminum and alpha-pyridoin complex

Kim WS Lim JH Lee BJ Oh Y Kwon YS

Synthesis and electroluminescent property of aluminum and alpha-pyridoin complex

Kim WS 1Lim JH 2Lee BJ 3Oh Y Kwon YS
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作者信息

  • 1. Inje Univ, Dept Chem, Kimhae 621749, South Korea
  • 2. Dongeui Univ, Dept Chem, Pusan 614714, South Korea
  • 3. Dong A Univ, Dept Elect Engn, Pusan 604714, South Korea
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Abstract

A novel light-emitting aluminum complex (PAI) containing the dihydroxy derivative of trans-1,2-dipyridylethene, alpha-pyridoin, was synthesized and its electroluminescent (EL) properties characterized. The chemical structure of the complex was elucidated by FTIR, UV-Vis and XPS. The complex showed thermal stability up to 350 degrees C under nitrogen flow by TGA. The photoluminescence (PL) was measured from PAI cast film on quartz plate. Electroluminescent device having the structure of ITO/TPD/PAI/Al was fabricated by vacuum deposition, where N, N-bis(3-methylphenyl)-N, N-diphenylbenzidine (TPD) was used as a hole transporting layer. The device emitted blue-green light of around 480 nm. The maximum luminance of 38 cd/m(2) and current density of 0.09 mA/cm(2) were observed at 34 V.

Key words

aluminum complex/photoluminescence/electroluminescence/alpha-pyridoin/EMITTING LAYER/EMISSION/DIODES/FILMS

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出版年

2005
Journal of nonlinear optical physics & materials

Journal of nonlinear optical physics & materials

ISTP
ISSN:0218-8635
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