首页|A selective and stable vapochromic system constructed by pillar [5] arene-based host-guest interactions
A selective and stable vapochromic system constructed by pillar [5] arene-based host-guest interactions
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The development of new strategies for the construction of highly selective and stable vapochromic system is still in great demand. Here, we present a highly selective and stable vapochromic system constructed by pillar[5] arene-based host-guest interactions between a pillar[5]arene (EtP5) and a phenazine derivative. The present material in this work showed specific selective responsiveness to chloroform vapor. The resultant dark orange solid sample was highly stable, which can maintain the color in air for at least two months at room temperature. Moreover, CHCI3 vapor responsive thin film and light-emitting diode (LED) was successfully prepared by coating the EtP5Dl complex on a glass sheet and a commercially available UV-LED. This work provided a new approach for the design and construction of selective and stable vapochromic systems with obvious color changes using pillar[5] arene-based host-guest interactions.
Vapochromic behaviorPhenazine derivativepillar[5]areneHost-guest interactionsThin film
Bingbing Shi、Weichun Li、Peng Qin
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Key Laboratory of Eco-functional Polymer Materials of the Ministry of Education, Key Laboratory of Eco-environmental Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, Gansu, 730070, PR China