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Industrial Crops and Products
Elsevier Science Publishers
Industrial Crops and Products

Elsevier Science Publishers

0926-6690

Industrial Crops and Products/Journal Industrial Crops and ProductsSCIISTPEI
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    Structural, physical and degradation characteristics of polyvinyl alcohol/ esterified mung bean starch/gliadin ternary composite plastic

    Su, ChunyanZhang, XiuyunGe, XiangzhenShen, Huishan...
    13页
    查看更多>>摘要:Biodegradable composite plastics with better performance can replace synthetic polymer materials in packaging fields such as food and industry. In this study, solvent casting produced different proportions of composite plastics based on polyvinyl alcohol (PVA), esterified starch, and gladin. Pure PVA plastics had high elongation at break value and light transmittance. The PVA/starch/ gliadin plastics had lower hydrophilicity, higher tensile properties, and higher biodegradability despite having a lower elongation at break than the pure PVA plastics. Scanning Electron Microscope, Atomic Force Microscopy, X-ray diffraction, Fourier Infrared Spectra, and light transmittance showed that the PVA/starch/gliadin plastic had good compatibility through the hydrogen bond formation. Various proportions of plastics exhibited different colors due to the different component ratios. Simultaneously, as the content of esterified starch increased, the melting enthalpy and crystallization enthalpy of composite plastics showed an increasing trend. When the PVA accounted for 25% and the starch/gladin was 75%/25%, the hydrophilicity of composite plastics was the lowest, and significantly lower than that of PVA plastics. When PVA accounted for 50% and starch/gladin was 75%/25%, the tensile properties of ternary composite plastics were the highest; when PVA accounted for 75%, and starch accounted for 25%, the elastic modulus of PVA/starch plastics was the highest. Moreover, composite plastics had a higher biodegradability than pure PVA plastics. The outstanding advantages of environment-friendly PVA/starch/gliadin plastics in different proportions can meet various aspects of actual production, such as water-sensitive goods packaging and heavy object bearing.

    Terpene synthase gene expression evaluation through RT-qPCR in Thymus caespititius

    Rodrigues, Carolina FerroTrindade, HelenaTenreiro, RogerioTenreiro, Ana...
    9页
    查看更多>>摘要:Thymus caespititius Brot. is an interesting aromatic plant due to the valuable monoterpenes it produces considering their properties and biological activities. Several chemotypes have been identified in this species, however, essential oil composition can vary throughout the year in the terpenes' relative percentage. The first objective was to evaluate chemical stability, based on a 20-month survey in essential oil (EO) composition through GC and GC-MS, in two accessions belonging to the carvacrol chemotype, Tc2 and Tc4. Together with this evaluation, a quantitative study of gene expression was performed through reverse transcription quantitative PCR (RT-qPCR), for the most important genes involved in the biosynthesis of gamma-terpinene (precursor of thymol and carvacrol), TcTPS2 and TcTPS4, and alpha-terpineol, TcTPS5. This second objective addressed the correlation between seasonal EO variation and terpene synthase gene expression patterns and compared the trends of seasonal variation between both plant accessions. The results show 22, 48 and 90-fold variation in gene expression for TcTPS2, TcTPS4 and TcTPS5, respectively. Expression of TcTPS5 was much more variable than those coding for gamma-terpinene synthase. The two accessions evaluated showed Tc2 had a more stable gene expression compared to Tc4. Although gene expression and terpene accumulation were in accordance for most timepoints, no significant overall correlation could be found. Our results suggest a transcriptional regulation for TcTPS2 and TcTPS4. For TcTPS5 regulation at post transcriptional level must be present, accounting for differences in the alpha-terpineol relative amount and adding new layers of complexity in specialized metabolism. Further studies should be pursued to identify all the players involved in controlling the final bouquet of essential oil composition.

    Structural evolution during corn stalk acidic and alkaline hydrogen peroxide pretreatment

    Xia, YingLiu, QiyingHu, XiaohongLi, Xu...
    11页
    查看更多>>摘要:Oxidative pretreatment is a promising strategy for biomass utilization due to its excellent performance and economic costs. Insights into lignocellulose recalcitrance are essential to further develop biomass manufacture. To understand structural recalcitrance, we performed systematic characterizations after mild hydrogen peroxide pretreatment in alkali or Lewis acid environments, followed by enzymatic hydrolysis to obtain higher glucose yields than raw materials. Results indicated that hydrogen peroxide pretreatment in saturated calcium hydroxide solution effectively removed lignin through cleavage of the lignin-carbohydrate complex and part C-C linkages in the middle lamella. The ferrous sulfate solution induced hemicellulose solubility, and the partially oxidized lignin was depolymerized under hydrogen peroxide pretreatment. The solvent could then be used for subsequent hydrolysis and cellulose conversion. It was demonstrated that hydrogen peroxide pretreatment is an effective and promising method for refining lignocellulose under an alkaline environment and is suitable for subsequent cellulose conversion in ferrous sulfate solution.

    Tannic acid modified hemicellulose nanoparticle reinforced ionic hydrogels with multi-functions for human motion strain sensor applications

    Gong, XiaoqiFu, ChenglongAlam, NurNi, Yonghao...
    9页
    查看更多>>摘要:Recently, biomass-derived materials, such as cellulose and lignin have gained popularity in the development of value-added products, such as hydrogel-based sensors. In fact, many studies have been reported on the inclusion of cellulose or lignin or their derived products for the preparation of hydrogels and their sensing applications, hemicelluloses-based hydrogels and their sensing applications are rare. In this study, we used a hemicellulose sample extracted from a bleached bamboo kraft pulp, to prepare hemicellulose nanoparticles (HC nanoparticles), then modified the HC nanoparticles with tannic acid to form tannic acid modified hemicellulose nanoparticles (TA@HC). Subsequently, the TA@HC nanoparticles were applied as nanofillers in the fabrication of ionic PAA-TA@HC-Al3+ hydrogels. The hydrogel integrates covalent PAA bonds with multiple non-covalent coordination bridging. TA@HC nanofillers, which have catechol-rich tannic acids on the surface, act as strength enhancers and dynamic link bridges, as well as imparting self-healing/adhesive properties to the ionic hydrogel. The resultant PAA-TA@HC-Al3+ ionic hydrogel exhibits high stretchability (1060%), toughness (as high as 1.52 MJ/m(3)) and self-recovery (as high as 87%). In addition, the use of TA@HC nanofillers allows the hydrogel to have reproducible self-adhesion to various materials, furthermore, the ionic hydrogel has excellent anti-ultraviolet, anti-oxidative and antibacterial properties. When applied as a wearable strain sensor, the as-fabricated ionic hydrogel has a high strain sensitivity (GF=8.34), and it can accurately monitor and distinguish between large movements and micro movements, even weak pulse and breathing.

    Embryogenic callus induction, cell suspension culture, and spectrum-effect relationship between antioxidant activity and polyphenols composition of Siraitia grosvenorii cultured cells

    Liu, ZeboZhu, XiaofengMohsin, AliYin, Zhongping...
    15页
    查看更多>>摘要:Siraitia grosvenorii (S. grosvenorii), a perennial vine of Cucurbitaceae family, has been widely used in medicine and food products. However, its application is hindered due to the limited output of natural and cultivated plants. Thus, to expand plant resource and application of S. grosvenorii, the current research study comprises embryogenic callus induction, development of suspension culture, and analysis on the spectrum-effect relationship between antioxidant activity and polyphenols composition of S. grosvenorii cultured cells. Adding 0.5 g.L- 1 ascorbic acid and 1.0 g.L- 1 choline could increase the induction rate from 0.75% to 68% and enhances the antioxidant enzyme activities of loose embryogenic calluses. A total of 15 polyphenols (14 flavonols and 1 phenolic acid) in the callus extracts were identified via liquid chromatography-mass spectrometry. Through Plackett-Burman's design and response surface methodology, optimal proportionings of plant growth regulator (PGRs) for cell suspension culture were obtained. With the optimized PGRs, the obtained cell biomass and polyphenols content were 32.18% and 13.86%, respectively, more than PGRs proportioning before optimization. Furthermore, a homogeneous and rapidly grown suspension cell culture was developed with a maximum biomass and polyphenols content of 25.5 g.L- 1 DW and 30.75 mg.g- 1 DW, respectively. The results of spectrum-effect relationships analysis indicated a strong linear correlation between 15 above-identified polyphenols and the antioxidation activity of the extracts. In addition, the partial least square method result revealed that all 15 polyphenols positively contributed to antioxidant capacity, including 3,4-di-p-coumaroyl, 5-tri-hydroxycoumaroyl quinic acid and kaempferol-3-O-Glc-7-O-Rha with vital roles. Our results indicated that the extracts from S. grosvenorii cell have excellent antioxidant activity, and therefore have potential applications in healthy food and daily cosmetics.

    Determining water use and crop coefficients of drip-irrigated cotton in south Xinjiang of China under various irrigation amounts

    Hou, XianghaoFan, JunliangZhang, FucangHu, Wenhui...
    13页
    查看更多>>摘要:Crop evapotranspiration (ETc) and crop coefficient (Kc) can vary among various geographical locations and cultivated species. Therefore, determining regional- and species-specific crop coefficients is fundamental for rational irrigation water management. A two-year field study was conducted in south Xinjiang of northwest China to estimate periodic ETc and reference evapotranspiration (ET0), and thus develop the regional crop coefficient (Kc) at various growth stages of fertigated cotton (Gossypium hirstum L. Xinluzhong No 67) under various irrigation amounts. ETc was determined by the soil water balance method, while ET0 was obtained using the FAO (Food and Agriculture Organization of the United Nations) Penman-Monteith model. The results indicated that increasing irrigation amounts resulted in increased seed cotton yields, but reduced crop water productivity (WP). The water consumption at flowering and boll setting stages accounted approximately for 60% of the seasonal water use of cotton under various irrigation amounts. The average locally developed Kc (Kc-local) values over two seasons were 0.38, 1.30 and 1.09 for initial, mid-season, and end-season stages, respectively. The locally developed initial Kc (Kc-local-ini) (0.38) was higher than the optimized initial-stage Kc (Kc-opt-ini) (0.23) and similar to the FAO recommended Kc (Kc-FAO) (0.35). The optimized Kc (Kc-opt) did not significantly differ from Kc-FAO at mid-season and end-season stages. The locally developed middle-stage Kc (Kc-local-mid) was 10% higher than the optimized middle-stage Kc (Kc-opt-mid) and the FAO recommended middle-stage Kc (Kc-FAO-mid), and the locally developed end-stage Kc (Kc-local-end) was approximately 82% higher than the optimized end-stage Kc (Kc-opt-end) and the FAO recommended end-stage Kc (Kc-FAO-end). The difference between Kc-local, Kc-opt and Kc-FAO was attributed to the variations of climate condition, cultivated variety and field management. Kc-local determined by the soil water balance method in the present study fully considered the regional conditions including weather, species and management practices, which can be adopted to guide the irrigation management in this region. This study provided credible cotton periodic Kc in the arid and semiarid regions of northwest China. A second-order polynomial relationship between cotton Kc and t/T (the days after emergence/the days of total cotton growth period) was established, which can provide a reference for the determination of local cotton Kc and irrigation management.

    High density planting and manure affect flower yield, corm characteristics, and volatile compounds of saffron (Crocus sativus L.)

    Esmaeilian, YaserAmiri, Mohammad BehzadNeamatollahi, Ehsan
    6页
    查看更多>>摘要:Special attention to the importance of medicinal plants in the world today in the agricultural, health and economic sectors is undeniable. Saffron is known as a very important medicinal and spice plant in the world. To study the response of the saffron plant to dense corm planting and different levels of manure, a two-year experiment was conducted in a split-plot complete block design with three replicates at Research Farm of University of Gonabad, Iran, during 2016-2019. The main factor consisted of 5, 10, and 15 cm spacing between plants on rows, and the sub-factor consisted of control (no manure) and application of 20, 40, and 60 t ha(-1) cow manure. The results showed that the maximum fresh flower yield in the first production year (74.5 kg ha(-1)) was achieved in the 40 t ha(-1) treatment under 5-cm corm spacing. In the second production year, maximum fresh flower yield (161.2 kg ha(-1)) was obtained from the 60 t ha 1 manure treatment under 5-cm spacing. The highest dry stigma yield (2.04 and 2.69 kg ha 1, in the first and second production year respectively) were obtained in plots with high planting density (5 cm spacing) and 60 t ha(-1) manure application. The highest daughter corm weights (3.18 and 3.23 g, in the first and second production year respectively) were obtained from the lowest corm planting density (15 cm). The 60 t ha 1 manure application resulted in the highest values for almost all traits. Therefore, to achieve suitable economic yield in saffron cultivation, application of 60 t ha(-1) cow manure under 20 x 5 cm planting density is suggested for areas with similar climatic and edaphic conditions to this experiment.

    Low-field benchtop versus high-field NMR for routine 31P analysis of lignin, a comparative study

    Feghali, E.Adriaensens, PeterVanbroekhoven, K.Vendamme, R....
    7页
    查看更多>>摘要:Over the past decade, advances in lignin characterization methods have led to a better understanding of lignin structure and reactivity. Novel chromatographic and spectrometric techniques, especially NMR, are now essential and routine for lignin analysis. Among these methods, quantitative 31P NMR spectroscopy proved itself as a powerful technique for the qualitative and quantitative analyses of diverse types of hydroxyl groups in lignin. Nevertheless, 31P NMR spectroscopy is typically accomplished using high-field NMR equipment that necessitates substantial investment and operational cost, limiting its ability to be employed as a routine tool for analysis and quality control in a production environment. In this work 31P NMR experiments were performed on several lignins, including technical, depolymerized, and modified lignins, using both an 80 MHz benchtop NMR and a 400 MHz high-field conventional NMR. Both NMR spectrometers showed similar results for both nonfunctionalized and modified lignins. This work demonstrates that low-field benchtop NMR is an excellent alternative to the conventional high-field NMR equipment to analyze the hydroxyl content of lignins.

    Ginkgo biloba L. seed; A comprehensive review of bioactives, toxicants, and processing effects

    Yang, Xiao-MingBoateng, Isaac Duah
    20页
    查看更多>>摘要:The Ginkgo biloba L. seeds (GBS) have been used for thousands of years. The GBS is used to produce functional beverages, fruit candies, and canned foods, among other items. Ginkgo biloba food supplements revenue in the world market accounts for over US$ 1.26 billion annually. Few reports have painstakingly summarized GBS. Thus, this review presents a systematic and current knowledge of GBS bioactives and toxicants and processing techniques applied during the last decade as success stories for education, research, and industrial scale. The methods used for extracting, separating, and identifying the main active constituents are explained. The factors impacting toxic and bioactive content and structure, including processing techniques, are outlined. Thermal technologies (steaming, roasting, microwaving, drying, and boiling), fermentation, membrane separation, nonthermal technologies (ultrasound, osmo-sonication, high hydrostatic pressure, and osmo-vacuum) treatment of GBS can reduce toxicity, and more active ingredients can also be retained. The severity of toxicity relies upon the processing method; therefore, it is essential to understand the GBS correctly as ginkgotoxins (MPN), ginkgotoxin5-glucoside (MPNG) and ginkgolic acid may initiate poisoning. As current works have shown that processing methods can reduce the toxicants (ginkgotoxins and ginkgolic acids) to a level unlikely to cause toxicity, GBS's detoxification efficiency needs further research. This will establish a complete understanding of GBS for food technologists, process engineers, chemists, physicians, academia or industry, and provide a scientific basis for its production.

    Boron deficiency disorders the cell wall in Neolamarckia cadamba

    Liu, TingtingLi, HuilingYin, QiKang, Lu...
    11页
    查看更多>>摘要:Boron (B) is an essential element for plant growth and development as it regulates numerous biological processes. Despite years of research on the role of B in regulating plant growth, changes in cell wall composition due to B deficiencyremain unclear. Here, we study B deficiency on the physiology and transcriptome of Neolamarckia cadamba, a fast-growing woody plant with diverse applications. B deficiency induces severe morphological and anatomical changes in N. cadamba including reduced seedling growth, significant inhibition of shoot tip growth and leaves. B deficiency also resulted in oxidative damage and decreasing B concentration in plant. In addition, enhancing activation of the phenylalanine ammonia lyase (PAL) and phenylpropanoid biosynthesis pathways resulted in increased shoot tip lignification. Pectin content decreased and the genes related to the synthesis of pectin and cellulose in mature leaves of N. cadamba changed expression levels in response to B deficiency. Moreover, BOR1, a potential B transporter, was differentially over-expressed under B deficiency in different tissues. Taking together, we can conclude that adaptive changes in N. cadamba cell walls to respond to B deficiency can potentially be utilized for genetic engineering and breeding for low B tolerance.