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Journal of industrial and engineering chemistry
The Korean Society of Industrial and Engineering Chemistry
Journal of industrial and engineering chemistry

The Korean Society of Industrial and Engineering Chemistry

1226-086X

Journal of industrial and engineering chemistry/Journal Journal of industrial and engineering chemistrySCIEICCRAHCI
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    Emerging chemo-biocatalytic routes for valorization of major greenhouse gases (GHG) into industrial products: A comprehensive review

    Sharma K.Nadda A.K.Park Y.-K.Banerjee P....
    20页
    查看更多>>摘要：? 2022 The Korean Society of Industrial and Engineering ChemistryClimate change is one of the major global concerns of 21st century, and the release of excessive greenhouse gases (GHG) is the foremost reason behind. It has become imperative to either capture excessive emission of GHG into the atmosphere or to develop advanced and efficient technologies for preventing further increase in its atmospheric concentration. Algal and microbial enzymes have been found to be effective in catalyzing the conversion of GHG to value-added products like biofuels, chemicals, polymers, biogas, and bioelectricity etc. However, these enzymes yield better catalytic activities when applied in combination with nano-materials having similar prowess for capturing and converting GHG. Replacing conventional chemical production through GHG capture and utilization affects emission of the same throughout the production chain (i.e., from cradle-to-gate). Herein, we analyze the technical potential of hybrid chemo-biocatalytic processes for GHG capture and their utilization to produce valuable industrial compounds. The study addresses the biosynthesis as well as genetic and metabolic engineering of different microbial enzymes for GHG sequestration and conversion. It also reviews recent literature of using different advanced materials for immobilization of enzymes and their subsequent application for GHG sequestration and conversion to valuable products.
      原文链接:
    • NSTL
    • Elsevier

    Recent progress and growth in biosensors technology: A critical review

    Chadha U.Selvaraj S.K.Bhardwaj P.Agarwal R....
    31页
    查看更多>>摘要：? 2022 The Korean Society of Industrial and Engineering ChemistryCrucial exploitation of biosensors has attained dominant significance in the meadow of drug innovation, drug identification, bio-remedy, food protection principles, security, protection, and ecological examination. It has direct to the innovation of specific and authoritative diagnostic tools that employ biological sensing elements as biosensors. Glucometers employ oxygen or hydrogen peroxide electrochemical recognition utilizing immobilized glucose oxidase electrodes, showing biosensors' invention. Current advances in biological methods and instrumentation relating to fluorescence tags to nano-materials have increased the responsive limit of biosensors. The use of aptamers or nucleotides, antibodies, peptide arrays, and molecule imprinted polymers offer tools to build up novel biosensors over the classical method. Integrated methods offer an improved perception for a buildup of precise and responsive biosensors with high regenerative potentials. Various biosensors ranging from nanomaterials polymers to microbes have more comprehensive potential applications. Combining multifaceted approaches to design biosensors that comprise the prospective for different usage is reasonably significant. In light of this, this review provides an overview of different types of biosensors being used, ranging from electrochemical and fluorescence tagged, nanomaterials, silica or quartz, and microbes for various biomedical and environmental applications with the future outlook of biosensor technology.
      原文链接:
    • NSTL
    • Elsevier

    Electrochemical sensing interfaces based on novel 2D-MXenes for monitoring environmental hazardous toxic compounds: A concise review

    Kim S.-Y.Ganesh P.-S.
    16页
    查看更多>>摘要：? 2022 The Korean Society of Industrial and Engineering ChemistryMXenes are two-dimensional (2D) layered materials of early transition metal carbides and/or nitrides used in a variety of technological applications. Due to its interesting morphology, high surface area, and biocompatibility, MXenes are the trending materials in the electrochemical and/or biosensor fabrication due to their novel and technically relevant properties. The present state of the art in the field of electrochemical sensors fabricated from MXenes is investigated in this review, with a focus on the detection of hazardous contaminants in the environment. And also, the comparison of fundamental properties of different nanomaterials with MXene was mentioned. To begin, we will look at how different synthesis techniques and surface functionalization alter MXene characteristics and, as a result, sensing performance. Second, MXenes are discussed as an electrode modifier for the detection of hazardous compounds, such as, phenolic moieties, pesticides and heavy metal ions. At the conclusion, the difficulties and future opportunities are discussed.
      原文链接:
    • NSTL
    • Elsevier

    Exploring metal-organic frameworks in electrochemistry by a bibliometric analysis

    Ye W.Yang W.
    11页
    查看更多>>摘要：? 2022 The Korean Society of Industrial and Engineering ChemistryConsidering the great significance of metal organic framework (MOF) in the field of electrochemistry and the knowledge gap in its development trend and research direction, this study collects 2,353 related publications indexed by Web of Science Core Collection published in the past 20 years. The analysis and mapping results reveal key information such as time series, countries/region, institutions, publication sources and citations. Furthermore, this study identifies the development trend and research hotspot of MOF, including nine valuable topics such as hydrogen storage, battery/capacitor materials, electrocatalysis and MOF composite energy storage. The findings and suggestions of this study can provide helpful reference and guidance for understanding the application and prospect of MOF in electrochemistry.
      原文链接:
    • NSTL
    • Elsevier

    Microfluidic free-flow electrophoresis: A promising tool for protein purification and analysis in proteomics

    Lee Y.Kwon J.-S.
    21页
    查看更多>>摘要：? 2022 The Korean Society of Industrial and Engineering ChemistryMicrofluidic free-flow electrophoresis (μFFE) is the most promising technique for proteomics. This method can perform real-time separation and detection of analytes in a small device where a continuous flow of carrier buffer is driven and an external electric field is applied perpendicular to the buffer flow. The capability of μFFE has motivated extensive applications pertaining to the pre-fractionation, enrichment, and higher-level purification of target proteins in biological systems. This review introduces the proteomics applications of the technique, along with a detailed theoretical overview, as follows. First, the principle and the band broadening involved in μFFE are explained. Next, materials for the fabrication of a μFFE device are described, followed by a summary of the online detection methods for μFFE. Finally, various applications of μFFE in proteomics fields are introduced, particularly focusing on microfluidic free-flow zone electrophoresis and microfluidic free-flow isoelectric focusing, the two major separation modes of μFFE.
      原文链接:
    • NSTL
    • Elsevier

    Novel polymeric additives in the preparation and modification of polymeric membranes: A comprehensive review

    Nasrollahi N.Ghalamchi L.Vatanpour V.Khataee A....
    25页
    查看更多>>摘要：? 2022 The Korean Society of Industrial and Engineering ChemistryOne of the basic challenges in polymeric membrane fabrication is the control of pore size and the porosity of the membranes. In this review paper, the role of polymeric additives is overviewed in membrane fabrication processes, such as the formation of pores in membranes, increasing permeability, hydrophilicity and even the creation of a desirable property such as antifouling and antibacterial properties. The polymeric additives could dissolve in water during the phase inversion process (a pore forming agent) or remain in the membrane matrix (hydrophilic and antifouling agent) or could have both roles. The additives could also act as proton exchanger and gas transport facilitating agents. This review concentrates on the introduction of new polymeric additives. In the blended membranes, the miscibility of chosen polymeric additives at the molecular levels make it a challenge to use the modification method. Molecular interactions between polymers such as hydrogen bonding and charge transfer play the main roles of the quality of blending. Different methods of polymer/co-polymer addition to the polymeric matrix of membranes are investigated to identify the best polymeric additives in various types of polymeric membranes including: pervaporation, contactor membrane, distillation membrane, etc. Moreover, the mixability of the additive polymer with the matrix polymer solution and the effectiveness of some functional additives are described in this review.
      原文链接:
    • NSTL
    • Elsevier

    Effects of hydrothermal parameters on the physicochemical property and photocatalytic degradation of bisphenol A of Ti-based TiO2 nanomaterials

    Chen Y.Yu J.Jia J.He H....
    12页
    查看更多>>摘要：? 2022 The Korean Society of Industrial and Engineering ChemistryEffects of hydrothermal parameters on morphology, crystal structure, light absorption, separation efficiency of photo-generated charge carriers, and photocatalytic removal of Bisphenol A (BPA) of Ti-based TiO2 nanomaterials were systematically investigated. Through changing hydrothermal parameters, TiO2 nanobelts, TiO2 nanosheets and TiO2 nanowires were prepared. With increasing NaOH concentration, hydrothermal temperature, and hydrothermal time, more TiO2 with (101) crystal plane grew on Ti substrate, resulting in higher crystallinity. The UV-light absorption enhanced with increasing NaOH concentration, but decreased with improving hydrothermal temperature, hydrothermal time, and HCl concentration. Variation of UV-light absorption was mainly affected by morphology, and UV-light absorption of TiO2 nanomaterials with different morphologies was arranged in order of nanobelts > nanosheets > nanowires. The hydrothermal growth of TiO2 nanomaterials on Ti plate conformed to Ostwald ripening mechanism. Variation trend of photo-generated current was consistent with that of BPA degradation, they both first increased and then decreased within investigated range. The optimal NaOH concentration, hydrothermal temperature, hydrothermal time, and HCl washing concentration were 1 M, 170℃, 28 h, and 0.1 M, respectively. Under this condition, Ti-based TiO2 nanosheets exhibited the highest BPA removal efficiency (92.7%), which was due to highly ordered nanosheet structure, good crystallinity, appropriate UV-light absorption and high separation efficiency of electron-hole pairs.
      原文链接:
    • NSTL
    • Elsevier

    Calculating osmotic pressure of liquid mixtures by association theory for sustainable separating of solvents by membrane processes

    Jalaei Salmani H.Karkhanechi H.Jeon S.Matsuyama H....
    10页
    查看更多>>摘要：? 2022 The Korean Society of Industrial and Engineering ChemistryRecent years, the separation of organic liquid mixtures achieved by organic solvent nanofiltration (OSN), organic solvent reverse osmosis (OSRO), and organic solvent forward osmosis (OSFO) has gained a great momentum. In the methods, it is of particular importance to know the osmotic pressure of liquid mixtures for the correct process design. Although the Van't Hoff law is frequently employed to estimate the osmotic pressure of such mixtures, unprecedented serious errors might be added to the results. In this study, the osmotic pressure of numerous binary liquid mixtures is predicted using the original definition of osmotic pressure along with the cubic plus association (CPA) equation of state (EoS) and the Van't Hoff equation at various temperatures and compositions. CPA EoS considers hydrogen bonding effects in associating compounds (those with hydrogen bonds such as water and alcohols). The obtained results reveal that unlike the Van't Hoff equation (the average deviation = 19.95 bar), the original definition of osmotic pressure with the aid of CPA EoS (the average deviation = 3.86 bar) can properly predict the osmotic pressure of the studied mixtures. Our findings are beneficial for various techniques utilized in the separation of organic liquid mixtures.
      原文链接:
    • NSTL
    • Elsevier

    Ultra-sensitive, selective and rapid carcinogenic Bisphenol A contaminant determination using low-dimensional facile binary Mg-SnO2 doped microcube by potential electro-analytical technique for the safety of environment

    Rahman M.M.Asiri A.M.Alfaifi S.Y.Ahmed J....
    8页
    查看更多>>摘要：? 2022 The Korean Society of Industrial and Engineering ChemistryHerein, a novel composite material (Magnesium co-doped Tin (IV) oxide; MTO) microcube was synthesized by a simple solution method in basic phase and successfully characterized. It has been used the Fourier Transform Infrared Spectroscopy (FTIR), X-ray Photoelectron Spectroscopy (XPS), X-ray Diffraction (XRD), Field Emission Scanning Electron Microscope (FESEM), and Energy-Dispersive Spectroscopy (EDS) techniques for the characterization of MTO. The MTO microcube was used later to modify gold-coated μ-chips to detect unsafe toxin, bisphenol A (BPA) in aqueous medium. Notable sensing performance was achieved with excellent sensitivity (1.63 μAμM?1cm?2), fast response time (～11 s), wide linear dynamic range (LDR = 0.10 nM – 1.0 mM: R2 = 0.9997), ultra-low detection limit (2.7 ± 0.1 pM at S/N = 3) and excellent reproducibility and repeatability for the MTO/Au/μ-Chip sensor. This MTO fabricated gold-coated μ-chip was further applied with appropriate quantification and determination results in real environmental sample analyses.
      原文链接:
    • NSTL
    • Elsevier

    Synthesis of surface-tuned polyacrylonitrile particles and its application to CO2 separation

    Kwon T.-G.Jun Kim B.Wook Kang S.Hyeon Jo O....
    6页
    查看更多>>摘要：? 2022 The Korean Society of Industrial and Engineering ChemistryWe synthesized the surface-tuned polyacrylonitrile (PAN) colloid particles as sulfate ions with a size of 75.6 nm. The synthesized PAN particles were introduced into a polymeric membrane for CO2/N2 separation. Poly(ethylene oxide) (PEO) was used as the polymer matrix. The PEO/PAN colloid composite membranes showed an improved ideal CO2 selectivity of 23, whereas the PEO membrane showed a selectivity of 6.7. This improved separation performance is attributable to the difference in solubilities of CO2 and N2 due to the presence of polar groups on the colloid surfaces, resulting in the enhanced separation performance.
      原文链接:
    • NSTL
    • Elsevier