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材料科学技术(英文版)
材料科学技术(英文版)

胡壮麟

月刊

1005-0302

jmst@imr.ac.cn

024-83978208

110016

沈阳市沈河区文化路72号

材料科学技术(英文版)/Journal Journal of Materials Science & TechnologyCSCDCSTPCD北大核心EISCI
查看更多>>本刊简称《JMST》,(ISSN 1005-0302,CN 21-1315/TG)。1985年创刊。是中国科协主管,中国金属学会,中国材料研究学会和中国科学院金属研究所联合主办的国际性英文期刊,以“加强国际交流,扩大学术影响,服务经济建设”为办刊宗旨,刊登世界各国的具有创新性和较高学术水平的原始性论文,并设有物约综述、快报、简讯及国内外材料界杰出学者简介等栏目,内容包括金属材料、无机非金属材料、复合材料及有机高分子材料等。
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    On the low cycle fatigue behaviour of an Al-Zn-Mg-Cu alloy processed via non-isothermal ageing

    Guangyi GuoGuofu XuYuan TangZhihao Zhao...
    227-238页
    查看更多>>摘要:The low cycle fatigue behaviour of an Al-Zn-Mg-Cu alloy processed via non-isothermal ageing(NIA)was examined at different strain amplitudes.We showed that NIA improved the low cycle fatigue life(more than 7000 cycles)by optimising the precipitate configuration within 5.5 h while maintaining comparable mechanical properties(570 MPa for tensile strength)and conductivity(nearly 39%IACS)to conventional isothermal ageing,simultaneously.Experimental observation combined with molecular dynamic simula-tion revealed that precipitation configuration manipulated by NIA had a crucial effect on fatigue resis-tance.A great number of repeatedly sheared and locally destructed GP zones enhanced co-planar slip and slip localisation in the under-aged alloy during the early stage of NIA,responsible for the dramatic displacement steps on the surface and resultant poor fatigue performance.As the NIA further proceeded,moderately coarsened precipitates with an average dimension of 6.0 nm and elevated number density ef-fectively impeded the dislocation movement and weaken the slip localisation to a great extent,improving the fatigue performance within a few hours.

    Grain-boundary segregation and grain growth in nanocrystalline substitutional solid solution alloys

    Fawei TangChao HouHao LuZhi Zhao...
    239-249页
    查看更多>>摘要:A model for describing solute segregation at grain boundaries has been developed for substitutional solid solution alloys,which integrates multiple factors from atomic to microstructural scales.A concept of mo-lar Gibbs free energy of segregation was introduced to evaluate the segregating capability of the solute elements in a closed system,through which the influences of grain boundary structure,grain size,ma-terial composition,and external conditions were described.Based on the evaluation of various energy forms related to solute segregation and grain growth processes,the nature of the thermal stabilization of nanograin structures by solute segregation was disclosed.A criterion for the destabilization of nanostruc-tures,which is determined by the competition of the change rates between the molar Gibbs free energy of segregation and the total energy of grain boundaries with grain size,has been proposed.This study provided guideline to achieve high-temperature stability of nanograin structures of solid solution alloys even for the weakly segregating nanocrystalline systems.

    Enhanced antibacterial activity,corrosion resistance and endothelialization potential of Ti-5Cu alloy by oxygen and nitrogen plasma-based surface modification

    Xiaotong ZhaoJiali HuJingjun NieDafu Chen...
    250-264页
    查看更多>>摘要:Antibacterial Ti-5Cu alloy is a promising substitute material for Ti-made cardiovascular implants,so its surface engineering is crucial to expediting clinical implementation.Given the antibacterial and cardiovas-cular biological benefits of Cu2+and titanium-nitride-oxide(TiNxOy)coatings,a Cu2O/CuO-TiNxOy coating with upregulated Cu2+release was successfully deposited on Ti-5Cu alloy for the first time using oxygen and nitrogen plasma-based surface modification.The superhydrophilic and nanostructured Cu2O/CuO-TiNxOy coating had a dense structure and was well bonded to the substrate,resulting in enhanced cor-rosion resistance,while CuO/Cu2O in the coating released Cu2+faster than Ti2Cu phase in the matrix.More gratifying,the coating demonstrated perfect antibacterial properties(R>99.9%against S.aureus),owing primarily to direct contact sterilization of Cu2O/CuO.The most encouraging phenomenon was that the coating dramatically accelerated HUVEC adhesion(1.4 times),proliferation(RGR:106%-116%),and particularly migration(RMR:158%-247%)compared with the control Ti.The coating extract also signifi-cantly stimulated in vitro angiogenesis capacity.The rapid endothelialization for Cu2O/CuO-TiNxOy coating was attributed to the surface nanostructure and Cu2+/NO2-release,which upregulated the angiogenesis-related gene expression of HIF-1α,VEGF,and eNOS to increase VEGF secretion and NO production.All of the findings indicated that the Cu2O/CuO-TiNxOy coating could enhance the corrosion resistance,an-tibacterial properties,and endothelialization potential of Ti-Cu alloy,displaying great clinical potential in cardiovascular applications.

    Tunning the bandgap of MnO2 homojunction by building active high-index facet to achieve rapid electron transfer for enhanced photocatalytic sterilization

    Tao ZhangBo LiChaofeng WangShuilin Wu...
    265-275页
    查看更多>>摘要:Photocatalysis has been a research hotspot in recent years,and the design and modification of photocat-alysts have been the key points.Common methods for designing photocatalysts,including constructing heterojunctions and homojunctions,have been developed on the basis of heterojunctions.In this study,two homojunctions of manganese dioxide(MnO2),including a high-index crystal plane homojunction and a general homojunction,are prepared using a stepwise hydrothermal method.Using a capping agent,the high-index crystal surface of the MnO2 is exposed.It is found that the electron transport efficiency be-tween the two components of the homojunction with high-index planes is higher and the adsorption capacity of the oxygen is stronger,which leads to higher photocatalytic efficiency.In addition,the newly designed high-index homojunction is used for the treatment of bacterial infections,and it kills Staphy-lococcus aureus(S.aureus)and Escherichia coli(E.coli)at rates of 99.95%±0.04%and 99.31%±0.25%,respectively.It also has excellent therapeutic effects on mouse wounds,which implies superb practical application value.This work provides a new strategy for the improved design of homojunctions and the application of photocatalytic materials.

    Toward tunable shape memory effect of NiTi alloy by grain size engineering:A phase field study

    Bo XuChong WangQingyuan Wang
    276-289页
    查看更多>>摘要:The inelastic deformations of shape memory alloys(SMAs)always show poor controllability due to the avalanche-like martensite transformation,and the effective control for the deformation of precision de-vices has been not yet mature.In this work,the phase field method was used to investigate the shape memory effects(SMEs)of NiTi SMAs undergoing grain size(GS)engineering,to obtain tunable one-way and stress-assisted two-way SMEs(OWSME and SATWSME).The OWSME and SATWSME of the systems with various gradient-nanograin structures and bimodal grain structure,as well as that with geometric gradients were simulated.The simulated results indicate that due to the GS dependences of martensite transformation and reorientation,the occurrence and expansion of martensite reorientation,martensite transformation and its reverse can be efficaciously controlled via the GS engineering.When combining the GS engineering and geometric gradient design,since the effects of GS and stress gradient can be su-perimposed or competing,and the responses of martensite reorientation,martensite transformation and its reverse to this are different,the OWSME and SATWSME of the geometrically graded systems with various nanograin structures can exhibit different improvements in controllability.In short,the reorienta-tion hardening modulus during OWSME is increased and the transformation temperature window during SATWSME is widened by GS engineering,indicating the improved controllability of SMEs.The optimal GS engineering schemes revealed in this work provide the basic reference and guidance for designing tun-able SMEs and producing NiTi-based driving devices catering to desired functional performance in various engineering fields.

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