首页|3种改性剂对大白藤的增强改性研究

3种改性剂对大白藤的增强改性研究

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为了提高棕榈藤材的物理力学性质,选择大白藤为研究对象,分别选用甲基丙烯酸甲酯(MMA)、锡铋镉铅合金(SBCPA)和糠醇(FA)作为改性剂,采取改性试剂种类、浸渍量、处理温度和处理时间四因素三水平进行正交试验.通过预试验发现,试件浸渍MMA、FA和SBCPA的最大浸渍量分别可达到35%、70%和200%左右.研究结果表明:3种改性处理的大白藤材主要物理力学性能均有不同程度改善,其中抗弯弹性模量(MOE)、抗弯强度(MOR)、顺纹抗压强度(USCPG)、顺纹抗剪强度(SSPG)和基本密度(BD)分别增加了 8.3%~64.2%、28.0%~107.6%、30.5%~94.4%、3.8%~32.1%和 32.1%~220.7%,体积全干干缩率(VSOD)下降了 19.6%~75.4%.综合多因素确定最佳工艺为:改性试剂为锡铋镉铅合金,浸渍量为195%,处理温度是105 ℃,处理时间是2 h.按此工艺进行验证实验得出改性材的抗弯弹性模量、抗弯强度、顺纹抗压强度、顺纹抗剪强度、基本密度分别为4 350 MPa、181.2 MPa、77.8 MPa、12.3 MPa 和 1.612g·cm-3,较素材依次增加了 46.9%、102.9%、60.2%、12.2%和221.1%;体积全干干缩率为7.3%,较素材下降了 27.0%.此外,改性材的电导率(EC)、极限氧指数(LOI)也分别由0 S·m-1和27.7%增大至0.904 S·m-1和29.9%.经锡铋镉铅合金改性处理后,大白藤的基本密度、主要力学强度均显著提升,干缩性明显降低,导电性和阻燃性也有不同程度的改善.
Research on the enhanced modification of Calamus faberii by three modified reagents
In order to improve the physical and mechanical properties of rattan,Calamus faberii was taken as the research object,MMA(methyl methacrylate),SBCPA(Si-Bi-Cd-Pb alloy)and FA(furfuryl alcohol)were se-lected as modified reagents.An orthogonal experiment was arranged at three levels,including four factors,namely,modifier,impregnation amount,treatment temperature and treatment time.According to the pre-experiment,the maximum impregnation amount of the specimen impregnated with MMA,FA and SBCPA were about 35%,70%and 200%,respectively.The results showed that the main physical and mechanical properties of the three modi-fied C.faberii were modified to different degrees,MOE(modulus of elasticity),MOR(bending strength),USCPG(compressive strength parallel to grain),SSPG(shearing strength parallel to grain)and BD(basic density)increased by 8.3%-64.2%,28.0%-107.6%,30.5%-94.4%,3.8%-32.1%and 32.1%-220.7%,respectively,while VSOD(volume over-dried shrinkage ratio)dropped by 19.6%-75.4%.A combination of factors determining the best process were as follows:the modified reagent was SBCPA,the impregnation amount was 195%,the treat-ment temperature was 105 ℃,and the treatment time was 2 h.According to the verification experiment obtained the modified material,MOE,MOR,USCPG,SSPG and BD were 4 350 MPa,181.2 MPa,77.8 MPa,12.3 MPa and 1.612 g·cm-3,and increased by 46.9%,102.9%,60.2%,12.2%and 221.1%,correspondingly;VSOD was 7.3%,down 27.0%from the material.EC(electrical conductivity)and LOI(limit oxygen index)also increased from 0 S·m-1 and 27.7%to 0.904 S·m-1 and 29.9%,correspondingly.In conclusion,after the modification treatment of SBCPA,the BD and main mechanical strength of C.faberii were significantly improved,the VSOD was sig-nificantly reduced,and the EC and LOI were also modified to varying degrees.

Calamus faberii Becc.MMAFASBCPAmodification treatmentphysical and mechanical properties

汪佑宏、李子严、杨明亮、季毕超、余林鹏、江泽慧、田根林

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安徽农业大学材料与化学学院,合肥 230036

合肥拟牛贸易有限公司,合肥 230051

国际竹藤中心,北京 100102

大白藤 甲基丙烯酸甲酯 糠醇 锡铋镉铅合金 改性 物理力学性能

2024

安徽农业大学学报
安徽农业大学

安徽农业大学学报

CSTPCD
影响因子:0.412
ISSN:1672-352X
年,卷(期):2024.51(6)