首页|河沙表面改性絮凝去除水华铜绿微囊藻的研究

河沙表面改性絮凝去除水华铜绿微囊藻的研究

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[目的]研究十六烷基三甲基溴化铵(CTAB)、双烷基聚氧乙烯基三季铵盐(DPQAC)和聚二甲基二烯丙基氯化铵(PDMDAAC)3种季铵盐阳离子表面活性剂改性河沙对去除铜绿微囊藻的影响.[方法]通过系统研究S-CTAB样品的粒径、制备温度、老化时间、pH、投加量对除藻率的影响,并且通过对S-CTAB样品絮凝沉降速率的研究,探讨了河沙表面改性的除藻机理.[结果]相同条件制备的S-CTAB对铜绿微囊藻的去除效果高于S-DPQAC和S-PDMDAAC.CTAB与河沙的质量比为0.04 g/g、河沙粒径为200目、投加量为5 g/L、水浴温度为40℃制备的S-CTAB样品表现出对铜绿微囊藻最佳的去除效果.S-CTAB样品对铜绿微囊藻的去除机理可能原因是通过改性河沙对藻类的架桥网捕作用及河沙表面季铵盐离子对藻细胞的灭杀作用.[结论]该研究提出的河沙表面改性除藻技术具有良好的效果,为河沙表面改性去除水华藻提供了一定的理论基础.
Flocculation and Removal Study of Water Bloom Microcystis aeruginosa by Surface-modified Sediment
[Objective] The cetrimonium bromide,cationic surfactant and poly dimethyl diallyl ammonium chloride were directly applied to modify the sediment,which were also employed to remove M.aeruginosa.[Method] The present work focused on the influences of size,preparing temperature,aging time,pH and dosage of S-CTAB sample on the removal of M.aeruginosa.The removal mechanism of M.aeruginosa was proposed by studying the average settling velocity of S-CTAB.[Result] Removal effect of M.aeruginosa by S-CTAB was higher than that by S-DPQAC and S-PDMDAAC.When mass ratio of CTAB and sediment was 0.04 g/g,size of sediment was 200 meshes,dosage was 5 g/L,temperature was 40 ℃,the prepared S-CTAB showed the best removal effect on M.aeruginosa.Removal mechanisms of M.aeruginosa by S-CTAB were bridging and netting capture effect of the modified sediment on algae and killing effect of quaternary ammonium ion of sediment surface to algae cell.[Conclusion] The present flocculation technology shows excellent performance,which could providetheoretical basis for the removal of water bloom M.aeruginosa.

Algae bloomSedimentFlocculationM.aeruginosa

王晓雪、钟成华、熊万明

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重庆市南岸区环境监测站,重庆400060

重庆工商大学环境与生物工程学院,重庆400067

水华 河沙 絮凝 铜绿微囊藻

重庆市科技攻关计划项目重庆市科技攻关计划项目

CSTC2009AD7204

2015

安徽农业科学
安徽省农业科学院

安徽农业科学

影响因子:0.413
ISSN:0517-6611
年,卷(期):2015.(19)
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