安徽省蔬菜基地土壤和灌溉水中邻苯二甲酸酯的残留状况
Residual PAEs in Soil and Irrigating Water from Typical Vegetable Fields in Anhui Province
王梅 1褚玥 1段劲生 1董旭 1孙明娜 1肖青青 1杨通 1高同春1
作者信息
- 1. 安徽省农业科学院植物保护与农产品质量安全研究所,农业部农产品质量安全风险评估实验室(合肥),安徽科立特农药环境评价科技有限公司,安徽合肥230031
- 折叠
摘要
[目的]了解安徽省蔬菜基地土壤和灌溉水中邻苯二甲酸酯(PAEs)的残留状况,为农产品的质量安全监管提供科学依据.[方法]对合肥、滁州和马鞍山地区12个代表性蔬菜基地的土壤和灌溉水进行调查采样,利用气相色谱-质谱联用检测技术(GC-MS),分析了土壤和灌溉水中18种PAEs化合物的含量.[结果]土壤样品中检出了邻苯二甲酸二丁酯(DBP)、邻苯二甲酸二(2-乙基)己酯(DE-HP),其总含量为0.2043～0.483 8 mg/kg,以滁州基地最高;灌溉水样品中18种PAES均未检出.土壤中PAEs以DBP和DEHP为主,DBP含量已超过美国土壤控制标准.[结论]安徽省蔬菜基地土壤已受到一定程度的PAEs污染.
Abstract
[Obsjective] To estimate the residual risk of phthalate acid esters (PAEs)in soil and irrigating water from vegetable fields in Anhui Province to provide scientific basis for supervising quality and safety of argircultural products.[Method] 18 PAEs in soil and irrigating water samples from 12 typical vegetable fields in Hefei,Chuzhou and Maanshan regions were detected by gas chromatography-mass spectrometry (GC-MS).[Results] Dibutyl phthalate (DBP) and phthalate (2-ethylhexyl)ester (DEHP) were found in all soil samples;the total content ranged from 0.204 3 to 0.483 8 mg/kg in the three typical vegetable fields,and it was the highest in Chuzhou.None of 18 PAEs were found in irrigating water samples.The content of DBP in all soil samples exceeded US allowable soil concentration.[Conclusion] Soil from vegetable fields of Anhui Province has been polluted by PAEs to some extent.
关键词
邻苯二甲酸酯(PAEs)/蔬菜基地/土壤/灌溉水/安徽省Key words
Phthalate acid esters (PAEs)/Vegetable fields/Soil/Irrigating water/Anhui Province引用本文复制引用
基金项目
安徽省农科院学科建设项目(14A1126)
安徽省农科院科技创新团队项目(14C1105)
国家农产品质量安全风险评估重大专项项目(GJFP2015007)
国家农产品质量安全风险评估重大专项项目(GJFP2015014)
公益性行业科研专项(201403030)
出版年
2016
国家科技期刊平台
NSTL
维普
万方数据