摘要
[目的]研究藏药曲玛孜2种基原植物西伯利亚蓼和小大黄挥发油的化学组成。[方法]采用水蒸气蒸馏法和气相色谱－质谱（ GC－MS）联用技术鉴定藏药曲玛孜挥发油化学成分。[结果]从藏药西伯利亚蓼挥发油中共鉴定19个成分，包括萜类、芳香化合物、脂肪烃类等，其中主要含有植醇（35．81％）、植酮（13．28％）、萘（4．79％）、亚麻酸甲酯（3．46％）；藏药小大黄挥发油的主要成分为（Z，E）－2，13－十八烷二烯－1－醇（29．99％）、大黄酚（15．18％）、萘（13．98％）、棕榈酸（7．00％），结构类型涉及脂肪醇类、蒽醌类、萜类等29个成分。[结论]藏药曲玛孜2种基原植物西伯利亚蓼和小大黄挥发油中主要成分组成相差较大，该研究为揭示曲玛孜品种整理、资源保护和合理利用提供一定的化学基础。
Abstract
Objective] To study chemical composition of the essential oil of Tibetan medicine Qumazi.[ Method] Essential oil of Tibetan medi-cine Qumazi was identified by using water vapor distillation and GC-MS.[Result]The major components of Polygonum sibiricum, involving ter-penes, aromatic compounds and aliphatic hydrocarbons, were phytol (35.81%), phytone (13.28%), naphthalene (4.79%),methyl linole-nate (3.46%).Meanwhile, the essential oil of Rheum pumilum was mainly including in fatty alcohols, anthraquinones, terpenes and the main volatile components of Rheum pumilum were Z, E-2, 13-octadecadien-1-ol ( 29.99%), chrysophanol ( 15.18%), naphthalene (13.98%), n-hexadecanoic acid (7.00%).[Conclusion] Great diversities in the constituents were found between Polygonum sibiricum and Rheum pumilum.The research provided chemical basis for the understanding, resource protection and appropriate utilization of Tibetan medi-cine Qumazi.
基金项目
江西省卫生厅项目(2014 A020)
江西省民族药协同创新中心子课题(JXXT201402024)
江西中医药大学重点学科青年教师培养计划(2013 jzzdxk041)
江西中医药大学博士启动基金(2014BS010)
万方数据