食用植物油中17种邻苯二甲酸酯类化合物的测定
Determination of 17 Phthalates in Edible Vegetation Oil
杨卫花 1赵浩军 1徐幸1
作者信息
- 1. 大理州质量技术监督综合检测中心，云南大理671000
- 折叠
摘要
[目的]建立一种可满足植物油中17种邻苯二甲酸酯类化合物的检测方法。[方法]利用气相色谱三重串联四级杆质谱技术，建立了植物油中17种邻苯二甲酸酯类化合物检测方法并进行了样品测试。[结果]该方法对食用植物油中17种邻苯二甲酸酯类化合物的检测，线性范围为10～1000μg／L，线性相关系数均大于0．999，样品中的检出限最低达到0．2 mg／kg。17种组分3个浓度梯度（1．0、5．0和10．0 mg／kg）的平均回收率均在80．4％～110．9％，相对标准偏差在2．4％～8．3％。[结论]该方法简便、快速、检出限低、结果准确，可应用于核桃油、菜籽油、玉米油等实际样品中17种邻苯二甲酸酯类化合物的测定。
Abstract
[Objective] The aim was to establish a method for detecting 17 phthalates esters(PAEs) in edible vegetation oil.[Method] Amethod for the determination of PAEs in edible vegetation oil by gas chromatography coupled with triple quadrupole mass spectrometry(GC-MS-MS) was established and samples were tested.[Result] The linear range of detection changed from 10 to 1 000 μg/L (r >0.999).The detection limits of samples of the 17 kinds of PAEs were 0.2 mg/kg.The average recoveries of three different concentrations (1.0, 5.0and 10 .0 mg/kg) were ranged between 80.40% to 110.9% and the relative standard deviations were ranged from 2.4% to 8.3%.[Conclusion] This method is simple, quick, accurate, which can be applied to the determination of 17 PAEs in walnut oil, rapeseed oil, corn oil andother edible vegetation oil samples.
关键词
气相色谱三重串联四级杆质谱/食用植物油/邻苯二甲酸脂类/塑化剂Key words
Gas chromatography-triple quadrupole mass spectrometry ( GC-MS-MS)/Edible vegetation oil/Phthalates esters( PAEs)/Plasti-cizer引用本文复制引用
基金项目
云南省质量技术监督局科技计划项目(2013ynzjkj16)
出版年
2016
国家科技期刊平台
NSTL
维普
万方数据