气相色谱法测定水中丙烯腈
Determination of Acrylonitrile in Water with Gas Chromatography
杨剑波 1章雪明 1张琰 1黄芳1
作者信息
- 1. 苏州市农产品质量安全监测中心,江苏苏州215128
- 折叠
摘要
[目的]建立水中丙烯腈的气相色谱测定方法.[方法]采用小体积直接进样,用DB-FFAP毛细管柱程序升温分离,氢火焰离子化检测器检测,以保留时间定性,外标法定量.[结果]该方法相对标准偏差低于5.0％,加标回收率为95.7％～ 101.0％,标准曲线相关系数大于0.999,检出限为0.03 mg/L.[结论]该方法适用于地表水中丙烯腈的测定.
Abstract
[Objective] A gas chromatographic method was developed for the determination of acrylonitrile in water samples.[Method] Acrylonitrile was separated through DB-FFAP capillary column and determined by GC-FID.Retention time of the peak was used for qualitative analysis,while external standard method was used for quantitative analysis.[Result] The results indicated the relative standard deviation was less than 5.00％,and the average recovery was 95.7-101.0％.The correlation coefficient of the standard curve was more than 0.999,and the method detection limit was 0.03 mg/L.[Conclusion] This method can be used for the determination of acrylonitrile in water samples.
关键词
气相色谱/毛细管柱/丙烯腈Key words
Gas chromatography/Capillary column/Acrylonitrile引用本文复制引用
出版年
2016
国家科技期刊平台
NSTL
维普
万方数据