首页|电感耦合等离子体质谱法测定不同产地肉桂中的重金属元素

电感耦合等离子体质谱法测定不同产地肉桂中的重金属元素

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[目的]根据广西肉桂种植地域特点,测定广西肉桂产品中砷(As)、铅(Pb)、镉(Cd)、汞(Hg)、铜(Cu)、铬(Cr)、锌(Zn)、镍(Ni)8种重金属元素的含量,评估肉桂外源性有害物质安全风险.[方法]采用微波消解-电感耦合等离子体质谱法(ICP-MS),对广西肉桂主产区内43批肉桂的8种金属元素进行含量测定.[结果]样品中有7种重金属元素含量均未超标;而Cd元素含量普遍超标,超标率占抽样数的90.70%.重金属污染评价发现,6个产区肉桂中Cd元素污染严重,而均值指数法(PI)提示桂平市、岑溪市、藤县肉桂中8种重金属已处于中污染,平南县、东兴市、防城区肉桂处于轻污染状态,所有产区最大污染因子均是Cd.人体健康风险评估结果显示,6个产区肉桂中8种重金属的日摄入量(ADD)均低于每日摄入参考剂量,每种重金属的危害商(HQ)均低于1,提示不会对人体造成非致癌健康危害.桂平市、岑溪市、藤县这3个产区肉桂中8种重金属累加的危害指数(HI)大于1,理论认为口服这3个产地肉桂可能对人体造成非致癌健康风险.[结论]广西不同产地肉桂样品的重金属元素含量存在一定差异,所用方法快速准确、灵敏度高、重复性好,可用于肉桂中重金属元素含量的测定,为肉桂中重金属元素限量标准的制定提供依据.
Determination of Heavy Metal Elements in Cinnamomum cassia from Different Producing Areas by Inductively Coupled Plasma Mass Spectrometry
[Objective]According to the regional characteristics of Cinnamomum cassia planting in Guangxi,this study determined the contents of 8 heavy metal elements in cassia bark including As,Pb,Cd,Hg,Cu,Cr,Zn and Ni,evaluated the safety risk of C. cassia exogenous harmful substances.[Method]Using microwave digestion-inductively coupled plasma mass spectrometry ( ICP-MS),8 metal elements of 43 batches of cinnamon in Guangxi main producing region were determined.[Result]The content of 7 heavy metals in the sample did not exceed the stand-ard,the Cd content generally exceeded the standard,the overbid rate accounted for 90.70% of the sampling number. For heavy metal pollution evaluation in C. cassia,it was found that Cd pollution in C. cassia in 6 producing areas,the mean index method (PI) indicates that 8 kinds of heavy metals in C. cassia from Guiping City,Cenxi and Teng County were moderate pollution county,Pingnan County,Dongxing City and Fangcheng District were in a state of light pollution,the biggest pollution factor in all producing areas was Cd. The results of human health risk assessment showed that the daily intake of 8 heavy metals in cinnamon of the 6 producing areas was lower than the acceptable daily intake. The hazardous quotient HQ of each heavy metal was less than 1,suggesting that it will not cause non-carcinogenic health harm to human body. However,the harm coefficient HI value of 8 kinds of heavy metals in cinnamon from Guiping City,Cenxi City and Teng County was greater than 1,the theory was that oral administration of cinnamon in these three origins may cause non-carcinogenic health risks to human.[Conclu-sion]There are some differences in the heavy metal element content of cinnamon samples from different origins in Guangxi,the method in this study is fast and accurate,with high sensitivity and good repeatability,which can be used for the determination of heavy metal elements con-tent in C. cassia,and can provide a basis for the formulation of the limit standard of heavy metal elements in cinnamon.

Cinnamomum cassia in GuangxiHeavy metalMicrowave digestionICP-MSRisk assessment

劳苏海、徐章丽、韦壹灵、王丹、梁俊、刘新彩、罗贵文

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北海市农产品质量检测中心,广西北海536000

广西中医药大学,广西南宁530000

桂林市农业生态与资源保护站,广西桂林 541000

广西益谱检测技术有限公司,广西南宁530000

百色市农产品质量安全检测中心,广西百色533000

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广西肉桂 重金属 微波消解 电感耦合等离子体质谱法(ICP-MS) 风险评估

2024

安徽农业科学
安徽省农业科学院

安徽农业科学

影响因子:0.413
ISSN:0517-6611
年,卷(期):2024.52(18)