半导体技术2025,Vol.50Issue(1) :1-9.DOI:10.13290/j.cnki.bdtjs.2025.01.001

集成电路CMP中金属腐蚀复配缓蚀剂的研究进展

Research Progress of Compound Corrosion Inhibitors for Metal Corrosion in Integrated Circuit CMP

武峥 牛新环 何潮 董常鑫 李鑫杰 胡槟 李佳辉
半导体技术2025,Vol.50Issue(1) :1-9.DOI:10.13290/j.cnki.bdtjs.2025.01.001

集成电路CMP中金属腐蚀复配缓蚀剂的研究进展

Research Progress of Compound Corrosion Inhibitors for Metal Corrosion in Integrated Circuit CMP

武峥 1牛新环 1何潮 1董常鑫 1李鑫杰 1胡槟 1李佳辉1
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作者信息

  • 1. 河北工业大学 电子信息工程学院,天津 300130;天津市电子材料与器件重点实验室,天津 300130;河北省微电子超精密加工材料与技术协同创新中心,天津 300130;河北省微电子专用材料与器件工程中心,天津 300130
  • 折叠

摘要

在化学机械抛光(CMP)过程中,集成电路金属多层布线因受抛光液中化学试剂的腐蚀而经常导致表面缺陷的出现.将两种及以上能够产生协同缓蚀效果的化学试剂复配可以得到较单一试剂更强的缓蚀性能.介绍了多试剂协同腐蚀抑制的机理,总结了国内外多试剂协同中两种缓蚀剂、表面活性剂与缓蚀剂、两种表面活性剂的复配协同在集成电路CMP金属腐蚀抑制应用中的研究进展,并延伸到碳钢金属等防腐领域,最后对CMP领域中多试剂协同抑制的发展进行了展望.

Abstract

In the process of chemical mechanical polishing(CMP),the metal multilayer wiring of integrated circuits are often subjected to surface defects due to the corrosion by chemical reagents in the polishing solution.The compounding of two or more chemical reagents that can produce collaborative corrosion inhibition effect can obtain stronger corrosion inhibition performance than a single reagent.The mechanism of multi-reagent collaborative corrosion inhibition is introduced,and the research progress of multi-reagent collaboration at home and abroad such as the compounding collaboration of two inhibitors,surfactants and corrosion inhibitors and two surfactants in the application of CMP metal corrosion inhibition in integrated circuits is summarized,and extended to the corrosion protection fields such as carbon steel metal.Finally,the development of multi-reagent collaborative inhibition in CMP field is prospected.

关键词

缓蚀剂/表面活性剂/化学机械抛光(CMP)/协同作用/金属腐蚀抑制

Key words

corrosion inhibitor/surfactant/chemical mechanical polishing(CMP)/collaborative effect/metal corrosion inhibition

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出版年

2025
半导体技术
中国电子科技集团公司第十三研究所

半导体技术

北大核心
影响因子:0.232
ISSN:1003-353X
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