首页|新疆和田墨玉中石墨包裹体碳同位素组成研究

新疆和田墨玉中石墨包裹体碳同位素组成研究

Carbon Isotopic Composition of Graphite Inclusion in Black Nephrite Jade from Xinjiang

扫码查看
新疆地区是中国最重要的和田玉成矿区带,赋存大量优质原生和次生和田玉矿床.其中,新疆和田墨玉可以划分为两种典型类型,一种以阳起石为主要矿物,另一种则主要以透闪石和石墨为主要矿物,后者颜色通常由石墨包裹体导致.众所周知,石墨在有机和无机碳循环过程中发挥重要作用,对科学揭示地球深部碳循环具有重要科学指示意义,而和田墨玉中石墨包裹体则是研究新疆地区复杂背景下碳聚集、固定及循环的有利对象.但以往的研究重点关注了和田墨玉成因类型、形成机制等方面,针对石墨包裹体的碳质来源,尚未被厘定,不利于和田玉成矿规律和构造演化的完整科学认识.因此,本研究采用显微岩相学、电子探针、碳稳定同位素等技术手段,对新疆和田墨玉样品的矿物组成、石墨包裹体碳同位素特征进行了系统研究.结果表明,新疆和田墨玉的主要矿物组成为透闪石,副矿物或次要矿物组成为石墨、方解石、透辉石和磷灰石等;石墨碳稳定同位素揭示,新疆和田墨玉中石墨包裹体的δ13 CPDB处于-21.3‰~-8.5‰,平均值为-13.76‰,具有相对较重的碳同位素组成,指示石墨碳质来源具有有机和无机双重成因.结合区域地质环境,我们认为在古生代中酸性岩浆侵入到前寒武纪白云石大理岩过程中携带幔源重同位素碳,导致石墨和透闪石共同结晶或沉淀.本文研究为和田玉矿床成矿过程及地球深部碳循环方面提供独特视角.
Xinjiang is the most important metallogenic belt of nephrite jade in China,with a large number of high quality primary and secondary nephrite jade deposits.Two typical types of black nephrite jade from Xinjiang are classified.One is mainly composed of actinolite,and the other one is mainly composed of tremolite and graphite with its colour generally caused by graphite inclusions.It is well known that graphite plays an important role in the processes of organic and inorganic carbon cycle,which exhibits important scientific significance for the deep carbon cycle of the Earth,and the graphite inclusion is acted as a favorable object for the study of carbon accumulation,fixation and cycling under the complex background of Xin-jiang.However,previous studies mainly focused on the genetic types and formation mecha-nisms of nephrite jade,and the carbon sources of graphite inclusions have not been deter-mined,which is not conducive to the complete scientific understanding of the metallogenic regularity and tectonic evolution of nephrite jade.In this study,the mineral components and carbon isotope characteristics of graphite inclusions in black nephrites from Xinjiang were studied by means of microscopic petrography,electron probe microscopy,and carbon stable isotopes.The results show that the main mineral component of black nephrite jade is tremo-lite,and the accessory or secondary minerals are graphite,calcite,diopside,and apatite,etc.The carbon stable isotopes in graphite reveal that the δ13 CPDB values of graphite inclu-sions in black nephrite jade range from-21.3‰ to-8.5‰,with the average value-13.76‰.The δ13CPDB of graphite inclusions exhibits relatively heavy carbon isotopic com-positions,indicating that the carbon sources of graphite are both organic and inorganic.Combined with the regional geological environments,we infer that the relative heavy isotopic carbon derived from the mantle source was carried during the processes of intrusion of the Paleozoic intermediate-felsic magma into the Precambrian dolomite marble,leading to the crystallization or precipitation of graphite and tremolite.This study provides a new perspec-tive for the ore-forming processes of the nephrite jade deposits and deep carbon cycle of the Earth.

black nephrite jadeore-forming processesδ13 C stable isotopesmagmatic-hy-drothermal processesXinjiang

张存、马楠、王婉琦、陈淑祥、吴煜、刘金海

展开 >

齐鲁工业大学(山东省科学院)材料科学与工程学院,山东济南 250353

新疆中鉴珠宝玉石检测研究院,新疆乌鲁木齐 830018

和田墨玉 成矿过程 δ13C稳定同位素 岩浆热液 新疆

2024

宝石和宝石学杂志(中英文)
中国地质大学(武汉)

宝石和宝石学杂志(中英文)

影响因子:0.4
ISSN:2096-9120
年,卷(期):2024.26(z1)