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葡萄糖基碳的改性制备及其储能性能研究

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使用氯化铵改性葡萄糖水热碳化法,制备出了一系列以片状结构为主的碳基材料,提高了葡萄糖基碳材料的储能能力.通过改变氯化胺的加入量,碳基材料的形貌由球形转变为片状,当葡萄糖与氯化铵的摩尔比为 1:2时,所得材料的比表面积最大,为1187 m2/g,孔体积可达0.692 cm3/g.对该材料的电化学性能进行测试,结果表明:新的合成方法大大提高了材料的储能性能,在1A/g的电流密度下,材料的比电容能达到190 F/g.同时,在千次充放电后,材料的电容保持率能达到96.7%.
Preparation of modified glucose-based carbon and its energy storage properties
In this paper,a series of carbon-based materials with a predominantly sheet-like structure were prepared by hydrothermal carbonisation of ammonium chloride-modified glucose to improve the energy storage capacity of glucose-based carbon materials.By var-ying the addition of amine chloride,the morphology of the carbon-based materials was changed from spherical to flaky.The specific surface area of the resulting materials was maximized at 1187 m2/g with a pore volume of 0.692 cm3/g when the molar ratio of glucose to ammonium chloride was 1:2.The electrochemical properties of the materials were tested,and the results showed that the energy stor-age performance of the materials was greatly improved by adopting the new synthesis method,with the specific capacitance of the mate-rials reaching 190 F/g at a current density of 1 A/g.The capacitance retention rate of the material reached96.7%after 1,000 charge/discharge cycles.

glucoseporous carbonhydrothermal carbonizationenergy storage

杨慧敏、王卓、程永兴、陈俊宇、张妍兰、武宇航

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内蒙古科技大学化学与化工学院,内蒙古包头 014010

葡萄糖 多孔碳 水热碳化 储能

内蒙古自治区自然科学基金项目内蒙古自治区自然科学基金项目内蒙古自治区自然科学基金项目国家自然科学基金项目

2021MS020292021BS020112020BS050321902080

2024

内蒙古科技大学学报
内蒙古科技大学

内蒙古科技大学学报

影响因子:0.247
ISSN:2095-2295
年,卷(期):2024.43(2)