内蒙古科技大学学报2024,Vol.43Issue(3) :246-250.DOI:10.16559/j.cnki.2095-2295.2024.03.009

La-NiCo LDH复合材料的制备及电化学性能

Preparation and electrochemical properties of La-doped NiCo LDH composites

李琦 李成美 刘验娇 赫文秀
内蒙古科技大学学报2024,Vol.43Issue(3) :246-250.DOI:10.16559/j.cnki.2095-2295.2024.03.009

La-NiCo LDH复合材料的制备及电化学性能

Preparation and electrochemical properties of La-doped NiCo LDH composites

李琦 1李成美 1刘验娇 1赫文秀1
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作者信息

  • 1. 内蒙古科技大学化学与化工学院,内蒙古包头 014010
  • 折叠

摘要

层状双金属氢氧化物(Layered Double Hydroxide,简称LDH)是一种优良的超级电容器电极材料.理论上La掺杂可优化这种材料的性能,但具体影响尚未被揭示.因此,采用水热法制备了La3+掺杂镍钴双金属氢氧化物(La-NiCo LDH)复合材料.在此基础上,进一步采用XRD、XPS、SEM和电化学测试的方法研究了不同物质的量比La3+的掺杂对La-NiCo LDH复合材料显微结构及电化学性能的影响.La3+的引入使样品形貌由蜂窝状微球转变为花瓣状微球,材料的比电容得到了很好地改善.在1A/g的电流密度下,对样品进行La3+掺杂后,样品比电容提升由812 F/g至1 458 F/g.同时也提升了材料的导电性能.

Abstract

Layered bimetallic hydroxide is an excellent electrode material for supercapacitors.La-doping can theoretically optimize the properties of such materials.However,its specific effects have not yet been revealed.Therefore,La3+doped nickel-cobalt bimetallic hydroxide(La-NiCo LDH)was prepared by hydrothermal method.On this basis,the effects of La3+doping amount on the microstruc-ture and electrochemical properties of La-Nico LDH were studied by XRD,XPS,SEM and electrochemical tests.The introduction of La3+transforms the morphology of the sample from honeycomb microspheres to petal microspheres,and the specific capacitance of the material is greatly improved.At the current density of 1 A/g,the specific capacitance of the Ni-Co LDH material is 812 F/g.After do-ping with La3+,the specific capacitance of the Ni-Co LDH material is 812 F/g.The specific capacitance of the sample increases to 1 458 F/g.Meanwhile,the electrical conductivity of the material is also improved.

关键词

镍钴双金属氢氧化物/La3+/超级电容器/元素掺杂/电化学性能

Key words

nickel-cobalt bimetallic hydroxide/La3+/supercapacitor/element doping/electrochemical performance

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基金项目

内蒙古自治区科技计划项目(2020GG0151)

内蒙古自治区科技计划项目(2021GG0380)

内蒙古自治区直属高校基本科研经费项目(XM2022BT10)

出版年

2024
内蒙古科技大学学报
内蒙古科技大学

内蒙古科技大学学报

影响因子:0.247
ISSN:2095-2295
参考文献量4
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