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荔枝果皮花色苷稳定性研究

Study on the Stability of Litchi Pericarp Anthocyanins

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为了解荔枝果皮花色苷的稳定性,以'糯米糍'荔枝果皮为试验材料,分离纯化得到荔枝果皮花色苷,通过高效液相色谱-质谱(HPLC-MS)联用技术鉴定荔枝果皮中的主要花色苷,并研究温度、酚类、醛类、有机酸、金属离子和抗氧化剂对荔枝果皮花色苷稳定性的影响.结果表明:'糯米糍'荔枝果皮中的主要花色苷为矢车菊素-3-芸香糖苷;荔枝花色苷对热不稳定,低温有利于荔枝果皮花色苷的保存;没食子酸、香兰素、草酸、3,5-二硝基水杨酸、阿魏酸均对荔枝果皮花色苷具有辅色效应,并且在一定范围内浓度越高,作用也越强;金属离子Al3+对花色苷有良好的增色和稳定作用,2,6-二叔丁基对甲酚抗氧化剂对荔枝花色苷虽然有明显的增色效应,但不利于花色苷稳定性的维持.研究结果可为采后荔枝果皮色泽控制提供理论依据.
This study aimed to investigate the stability of litchi anthocyanins.'Nuomici'pericarp was collected and used as the experimental materials for lychee anthocyanins separation and purification,the main anthocyanins were identified by HPLC-MS combined technology,and the effects of temperatures,phenols,aldehydes,organic acids,metal ions and antioxidants on the stability of lychee anthocyanins were studied.The results showed that the main anthocyanin in'Nuomici'lychee pericarp was cyanidin-3-rutinoside,which was unstable at high temperatures,while beneficial for preservation at low temperatures.The gallic acid,vanillin,oxalic acid,3,5-dinitrosalicylic acid,and ferulic acid all presented synergistic effects as co-pigment on lychee anthocyanins,and the effects were stronger with increasing concentrations within a certain range.Furthermore,Al3+ions demonstrated significant color enhancement and stabilization properties for the anthocyanins.In contrast,the antioxidant 2,6-di-tert-butyl-4-methylphenol showed obvious color enhancement on lychee anthocyanins but negatively impacted the stability maintenance.The research results could provide theoretical basis for the post-harvest color control of lychee peri-carp.

litchi pericarpanthocyaninsco-pigmentbrowningstability

王春兰、张丹丹、蒋跃明、代庭锐

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中国科学院华南植物园,广东省应用植物学重点实验室,广东 广州 510650

中国科学院大学生命科学学院,北京 100049

赣南师范大学生命科学学院,江西 赣州 341000

荔枝果皮 花色苷 辅色剂 褐变 稳定性

2025

保鲜与加工
国家农产品保鲜工程技术研究中心(天津)

保鲜与加工

北大核心
影响因子:0.956
ISSN:1009-6221
年,卷(期):2025.25(1)