首页|pH传感型智能纺织品的制备与性能探究

pH传感型智能纺织品的制备与性能探究

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为了实现对环境pH值的精确和便捷式测量,研究制备了一种pH传感型智能纺织品.首先,利用静电纺丝技术将刚果红(Congo red)与溴酚蓝(Bromophenol blue)pH指示剂分别与聚丙烯腈(PAN)、热塑性聚氨酯(TPU)高分子聚物材料共混纺制出具有pH变色功能的纳米纤维膜R-PAN-TPU与B-PAN-TPU.然后使用热压方法将纳米纤维膜进一步与棉(Cell)基底织物结合,得到pH传感型智能纺织品R-PAN-TPU-Cell与B-PAN-TPU-Cell.经测试,刚果红pH传感器R-PAN-TPU-Cell接触pH值3~5 的酸溶液显示出明显的蓝紫色,而接触pH值 9~12的碱溶液则没有明显的显色变化.溴酚蓝pH传感器B-PAN-TPU-Cell接触pH值 3~5 的酸溶液显示出明黄色,接触9~12 的碱溶液则变为紫色.该织物型pH传感器不仅在环境监测领域能够起到有效的预警与防护作用,还具有循环可利用的特点.
Preparation and Performance Exploration of pH Sensing Intelligent Textiles
In order to achieve accurate and convenient measurement of environmental pH value,a pH sens-ing intelligent textile was prepared.Firstly,the nanofiber membranes R-PAN-TPU and B-PAN-TPU with pH color-changing function were fabricated by separately blending Congo red and Bromophenol blue pH indicators with polyacrylonitrile(PAN)and thermoplastic polyurethane(TPU)polymer materials by electrospinning tech-nology.Then the nanofiber membranes were further combined with cotton(Cell)substrate fabric by hot pressing method to obtain pH sensing intelligent textiles R-PAN-TPU-Cell and B-PAN-TPU-Cell.After testing,the Congo red-based pH sensor R-PAN-TPU-Cell displayed obvious blue-purple color when contacting pH 3-5 acid solution while no color change was observed when contacting pH 9~12 alkaline solution.The Bromophenol blue-based pH sensor B-PAN-TPU-Cell exhibited a vibrant yellow hue upon contact with acid solutions within the pH range of 3~5,and transitioned to a purple color when exposed to alkaline solutions with pH values ran-ging from 9~12.The intelligent textile-based pH sensor not only demonstrates its effectiveness in early warning and protection within the realm of environmental monitoring,but also possesses the characteristic of recyclable u-tilization.

pH sensingnanofiberelectrospinning technologyintelligent color-changing textileearly warning and protection

陈嘉轩、裔士钊、吴焕岭、王春霞、孙绪、唐盛、罗一宁

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盐城工学院 纺织服装学院,江苏 盐城 224051

pH传感 纳米纤维 静电纺丝技术 智能变色纺织品 预警与防护

2025

纺织科学与工程学报
成都纺织高等专科学校

纺织科学与工程学报

影响因子:0.262
ISSN:2096-5184
年,卷(期):2025.42(1)