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钒铬渣钙化焙烧—酸浸过程多组元浸出行为

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以钒铬渣钙化焙烧熟料为原料,探究了浸出pH值、浸出温度、浸出时间和浸出液固比对钒铬渣中钒以及铬、锰、硅、钛、铁组元浸出率(质量分数,下同)的影响。结果表明:在酸浸过程中浸出pH值为2。8、浸出温度为60℃、浸出时间为60 min、浸出液固比为5的条件下,钒浸出率达到87。81%,此时铬、锰、硅、钛、铁浸出率分别为0。44%,23。91%,2。28%,0。23%,0。03%;此外,延长浸出时间、提高浸出温度、适当增大浸出液固比均有利于钒的分离提取。
Multi-component leaching behavior of vanadium-chromium slag during calcification roasting-acid leaching
In this paper,using calcined clinker of vanadium-chromium slag as raw material,the effects of leaching pH value,leaching temperature,leaching time,and leaching liquid-solid ratio on the leaching rate ( mass fraction,the same below ) of vanadium,chromium,manganese,silicon,titanium and iron in vanadium-chromium slag were investigated.The results showed that during the acid leaching process,under the conditions of acid leaching pH value 2.8,leaching temperature 60℃,leaching time 60 min and liquid-solid ratio 5,the leaching rate of vanadium reached 87.81%.At this time,the leaching rates of chromium,manganese,silicon,titanium,and iron were 0.44%,23.91%,2.28%,0.23% and 0.03%,respectively.In addition,extending the leaching time,increasing the leaching temperature,and appropriately increasing the leaching liquid-to-solid ratio are all beneficial to the separation and extraction of vanadium.

vanadium-chromium slagcalcification roastingacid leachingleaching parametersleaching rate

刘孟霞、温婧、余唐霞、李芳芳、李菲菲、姜涛

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东北大学 冶金学院,沈阳 110819

钒铬渣 钙化焙烧 酸浸 浸出参数 浸出率

国家自然科学基金国家自然科学基金中国博士后科学基金

512174277522043092022M720683

2024

材料与冶金学报
东北大学

材料与冶金学报

北大核心
影响因子:0.516
ISSN:1671-6620
年,卷(期):2024.23(1)
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