材料与冶金学报2024,Vol.23Issue(2) :164-172.DOI:10.14186/j.cnki.1671-6620.2024.02.007

预变形Mg-Nd合金时效析出行为的原子尺度

Atomic-scale investigation of aging precipitation behaviors in pre-deformed Mg-Nd alloy

郭文祥 谢红波 任玉平 秦高梧
材料与冶金学报2024,Vol.23Issue(2) :164-172.DOI:10.14186/j.cnki.1671-6620.2024.02.007

预变形Mg-Nd合金时效析出行为的原子尺度

Atomic-scale investigation of aging precipitation behaviors in pre-deformed Mg-Nd alloy

郭文祥 1谢红波 1任玉平 1秦高梧1
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作者信息

  • 1. 东北大学 材料科学与工程学院,沈阳 110819;东北大学 材料各向异性与织构教育部重点实验室,沈阳 110819
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摘要

使用球差校正的高角环形暗场扫描透射电镜(HAADF-STEM)系统研究了预变形Mg-2.0%Nd(质量分数)合金 250℃等温时效 2h后的时效析出行为.结果表明,预变形产生的位错促进了第二相的形核,导致高密度且有别于传统沿{10(1)0}α 惯习面均匀分布的亚稳析出相的形成.原子尺度的表征结果表明,合金内部形成的析出链主要由βS′相和β1 相组成.此外,析出链中还含有少量的β″和βH′相,以及βL′相.这些片状或透镜状的βS'和 β1 相与α-Mg基体完全共格,且均具有一个{10(1)0}α 的惯习面,但沿[11(2)0]α,[1(2)10]α 和[(2)110]α 3 个方向非均匀分布.这些结果有望为形变调控合金的析出行为,提升合金力学性能提供理论指导.

Abstract

The precipitation behavior of the pre-deformed Mg-2.0% Nd(mass fraction)binary alloy isothermally aged at 250℃ for 2 h has been systematically investigated by means of aberration-corrected high angle annular dark field-scanning transmission electron microscopy(HAADF-STEM).It is determined that the dislocations generated by pre-deformation facilitate the nucleation of secondary phases,leading to the formation of high density metastable precipitates which are different from the traditional uniform distribution along the{10(1)0}α habit planes.Atomic-scale observation shows that the precipitate-chains within the matrix consist mainly of the βS′and β1 phases.In addition,the precipitate-chains contain small amounts of β″ and βH′phases,as well as the βL′phase.These lamellar or lenticular βS′and β1 phases are fully coherent with the α-Mg matrix,with a{10(1)0}α habit planes,but are non-uniformly distributed along-the three directions of[11(2)0]α,[1(2)10]α and[(2)110]α.These results are expected to provide theoretical guidance for controlling the precipitation behavior of alloys via deformation to enhance the mechanical properties.

关键词

镁合金/变形/时效硬化/析出/HAADF-STEM

Key words

magnesium alloys/deformation/aging hardening/precipitation/HAADF-STEM

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基金项目

国家自然科学基金青年基金项目(52101129)

出版年

2024
材料与冶金学报
东北大学

材料与冶金学报

北大核心
影响因子:0.516
ISSN:1671-6620
参考文献量35
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