材料与冶金学报2024,Vol.23Issue(6) :592-597,606.DOI:10.14186/j.cnki.1671-6620.2024.06.012

原始粉体对Mg-PSZ陶瓷电化学性能的影响

Effect of original powders on electrochemical property of Mg-PSZ ceramics

洪浩 刘涛 于景坤
材料与冶金学报2024,Vol.23Issue(6) :592-597,606.DOI:10.14186/j.cnki.1671-6620.2024.06.012

原始粉体对Mg-PSZ陶瓷电化学性能的影响

Effect of original powders on electrochemical property of Mg-PSZ ceramics

洪浩 1刘涛 1于景坤1
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作者信息

  • 1. 东北大学冶金学院,沈阳 110819
  • 折叠

摘要

分别利用固相烧结法和共沉淀法制备了摩尔分数为8%的MgO稳定ZrO2粉体,并在1 600 ℃下烧结2 h,获得了摩尔分数为8%的MgO部分稳定氧化锆陶瓷(8Mg-PSZ),考察了原始粉体对陶瓷体相含量、致密度、微观结构和离子电导率的影响.结果表明:原始粉体形貌对Mg-PSZ陶瓷性能的影响很大,原始粉体粒径越小、团聚程度越低,所获得的Mg-PSZ陶瓷四方相和立方相氧化锆含量(体积分数)、致密度越大,离子电导率越高;以NaOH溶液为沉淀剂、以共沉淀法合成的粉体为原料烧结得到的Mg-PSZ陶瓷具有最佳性能,体积密度为5.68 g/cm3,在650~950 ℃的测试范围内激活能为1.24 eV,950 ℃下离子电导率可达4.79 mS/cm.

Abstract

ZrO2 powders stabilized by 8%MgO(mole fraction)were prepared by solid-state sintering method and co-precipitation method,respectively,and 8%MgO-partially stabilized ZrO2 ceramics(8Mg-PSZ)were obtained by sintering at 1 600 ℃ for 2 h.The effects of the original powders on the phase content,density,microstructure,and ionic conductivity of the ceramics were investigated.The results show that the original powders morphology has a great influence on the properties of Mg-PSZ ceramics.The smaller particle size of the original powders,the lower degree of agglomeration,and the higher content(volume fraction)and density of tetragonal and cubic zirconia in Mg-PSZ ceramics,the higher the ionic conductivity.Using NaOH solution as precipitant,Mg-PSZ powders obtained by coprecipitation method have the best properties,the bulk density is 5.68 g/cm3,the activation energy is 1.24 eV in the testing range of 650~950 ℃,and the ionic conductivity can reach 4.79 mS/cm at 950 ℃.

关键词

氧化锆陶瓷/致密度/离子电导率

Key words

zirconia ceramics/density/ionic conductivity

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出版年

2024
材料与冶金学报
东北大学

材料与冶金学报

北大核心
影响因子:0.516
ISSN:1671-6620
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