首页|Ti-10Mo-6Zr-4Sn-3Nb在Hank's溶液中的腐蚀行为研究

Ti-10Mo-6Zr-4Sn-3Nb在Hank's溶液中的腐蚀行为研究

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Ti-10Mo-6Zr-4Sn-3Nb(Ti-B12)具有优良的力学性能,可作为生物医用材料使用.然而,对于Ti-B12的腐蚀行为,目前还缺乏研究.通过光学显微镜、X射线衍射和电化学测量研究了铸态、退火、形变3种工艺的Ti-B12的显微组织和在Hank's溶液中的腐蚀行为.结果表明,与铸态和形变态的Ti-B12相比,退火态Ti-B12具较低的腐蚀电流密度,具有更好的耐蚀性.而施加阳极电位后,退火Ti-B12在动电位极化和静电位极化试验中均表现出较高的钝化电位,较低的钝化电流密度,更高的氧空位扩散系数.这是因为退火态Ti-B12与铸态Ti-B12相比降低了硬度,细化了晶粒,消除了组织缺陷;而形变态Ti-B12在塑性形变过程中产生更多位错,产生β形变孪晶,伴有少量α沉淀相析出,组织硬度提高.这2种工艺与铸态Ti-B12相比组织发生显著变化,也展示出不同于铸态Ti-B12的腐蚀行为.
Corrosion behavior of Ti-10Mo-6Zr-4SN-3Nb in Hank's solution
Ti-10Mo-6Zr-4Snv-3Nb ( Ti-B12 ) exhibits excellent mechanical properties and can be used as a biomaterial.Currently, few research is available on the corrosion behavior of Ti-B12.This paper studies the microstructure and corrosion behavior of Ti-B12 in the as-cast, annealed, and deformed states in Hank' s solution by employing optical microscopy, X-ray diffraction, and electrochemical measurements.Our results indicate that, compared with the as-cast and deformed states of Ti-B12, the annealed Ti-B12 exhibits lower corrosion current density and better corrosion resistance.When subjected to an anodic potential, annealed Ti-B12 shows higher passivation potential, lower passivation current density, and a higher oxygen vacancy diffusion coefficient in both dynamic and static potential polarization tests.This is attributed to the fact that the annealed Ti-B12, compared to the as-cast Ti-B12, has reduced hardness, refined grains, and eliminated microstructural defects.Meanwhile, the deformed Ti-B12 undergoes plastic deformation, leading to more dislocations, the formation of β deformation twins, and a small amount of α precipitation, resulting in increased microstructural hardness.Both annealing and deformation processes significantly alter the microstructure compared to the as-cast Ti-B12 , demonstrating different corrosion behaviors than that of the as-cast Ti-B12 .

titanium alloycorrosion behaviorbiomedical

王博涵、郑传波、程军、陈靓瑜

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江苏科技大学 材料科学与工程学院, 江苏 镇江 212100

中国西北有色金属研究院 陕西省生物医用金属材料重点实验室, 西安 710016

钛合金 腐蚀行为 生物医用

国家自然科学面上基金项目

52271249

2024

重庆理工大学学报
重庆理工大学

重庆理工大学学报

CSTPCD北大核心
影响因子:0.567
ISSN:1674-8425
年,卷(期):2024.38(9)
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