磁性材料及器件2024,Vol.55Issue(2) :12-17.DOI:10.19594/j.cnki.09.19701.2024.02.003

Nb5+取代对高介电常数钇铁石榴石铁氧体磁性能的影响

Effect of Nb5+ substitution on the magnetic properties of yttrium iron garnet ferrite with high dielectric constant

胡智勇 余忠 李凌峰 张方远 李启帆 张晓峰 孙科 邬传健 蒋晓娜 兰中文
磁性材料及器件2024,Vol.55Issue(2) :12-17.DOI:10.19594/j.cnki.09.19701.2024.02.003

Nb5+取代对高介电常数钇铁石榴石铁氧体磁性能的影响

Effect of Nb5+ substitution on the magnetic properties of yttrium iron garnet ferrite with high dielectric constant

胡智勇 1余忠 1李凌峰 2张方远 2李启帆 1张晓峰 1孙科 1邬传健 1蒋晓娜 1兰中文1
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作者信息

  • 1. 电子科技大学材料与能源学院,四川成都 610054
  • 2. 东阳富仕特磁业有限公司,浙江东阳 322105
  • 折叠

摘要

采用传统氧化物烧结工艺制备高介电常数(ε′)钇铁石榴石铁氧体,考察不同烧结温度时Nb5+取代对材料显微结构、晶相、密度(d)、气孔率(p)、晶格常数(a)、饱和磁化强度(4πMs)、铁磁共振线宽(ΔH)和介电常数等磁性能的影响.结果表明,Nb5+取代使材料的晶粒尺寸略微增大;Nb5+取代对材料的晶相无明显影响,均为石榴石纯相;1020℃烧结时,随着Nb5+取代量x由0增大到0.075,4πMs从1882 G减小到1741 G,ΔH从149.3 Oe增大到180.2 Oe,烧结体密度从5.83 g/cm3减小到5.72 g/cm3,烧结体平均晶粒尺寸(D)从2.29 μm增加到2.38 μm,气孔率(p)从1.7%增大到3.0%,ε′无明显变化.

Abstract

High dielectric constant(ε′)yttrium iron garnet ferrites were prepared by traditional oxide sintering process.The effects of Nb5+ substitution on the microstructure,crystal phase,density(d),porosity(p),lattice constant(a),saturation magnetization(4πMs),ferromagnetic resonance linewidth(ΔH)and dielectric constant of the materials sintered at different temperatures were investigated.The results show that Nb5+ substitution slightly increases the grain size of the material.Nb5+ substitution has no obvious effect on the crystal phase of the material,which is pure garnet phase.When sintered at 1020℃,with the increase of Nb5+ substitution amount x from 0 to 0.075,4πMs decreases from 1882 G to 1741 G,ΔH increases from 149.3 Oe to 180.2 Oe,the density decreases from 5.83 g/cm3 to 5.72 g/cm3,the average grain size(D)increases from 2.29 μm to 2.38 μm,the porosity increases from 1.7%to 3.0%,and ε′ has no obvious change.

关键词

石榴石铁氧体/Nb5+取代/饱和磁化强度/铁磁共振线宽/介电常数

Key words

garnet ferrite/Nb5+ substitution/saturation magnetization/ferromagnetic resonance linewidth/dielectric constant

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出版年

2024
磁性材料及器件
中国西南应用磁学研究所

磁性材料及器件

影响因子:0.358
ISSN:1001-3830
参考文献量17
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