磁性材料及器件2024,Vol.55Issue(3) :62-68.DOI:10.19594/j.cnki.09.19701.2024.03.010

TbCu7型SmFe9熔淬合金的制备及元素掺杂对其热稳定性的影响

Preparation of TbCu7-type SmFe9 melt quenched alloy and influence of element doping on its thermal stability

黄珩 蔡伟 陈意顺 张昕琦 尉时通 郑精武 苏月斌 陈海波 乔梁 车声雷
磁性材料及器件2024,Vol.55Issue(3) :62-68.DOI:10.19594/j.cnki.09.19701.2024.03.010

TbCu7型SmFe9熔淬合金的制备及元素掺杂对其热稳定性的影响

Preparation of TbCu7-type SmFe9 melt quenched alloy and influence of element doping on its thermal stability

黄珩 1蔡伟 1陈意顺 1张昕琦 1尉时通 1郑精武 1苏月斌 2陈海波 1乔梁 1车声雷1
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作者信息

  • 1. 浙江工业大学材料科学与工程学院,磁电功能材料研究所,浙江杭州 310014
  • 2. 浙江皓翔矿业有限公司,浙江青田 323900
  • 折叠

摘要

采用熔淬法制备SmFe9合金,通过合金相组分和表面形貌分析,研究了熔炼时Sm的质量分数及熔体快淬时铜辊的转速对单一相SmFe9制备的影响,并探究了 Ti、Co、V掺杂对SmFe9合金热稳定性的影响.实验结果表明,Sm含量的降低及淬速的提高都有利于SmFe9相的生成,当Sm含量为22.3 wt%左右,辊速为51.84 m/s以上时即可形成具有单一相的SmFe9合金.在元素掺杂方面,相对于Co和V而言,Ti掺杂对于提高SmFe9的热稳定性具有积极作用,可以减少SmFe9合金的高温分解,抑制α-Fe的析出.

Abstract

SmFe9 alloy was prepared by melting quenching method.The influence of the mass fraction of Sm during melting and the speed of copper roller during rapid quenching on the preparation of single phase SmFe9 alloy was studied through analysis of alloy phase composition and surface morphology.The influence of Ti,Co,and V doping on the thermal stability of SmFe9 alloy was also investigated.The results showed that reducing the Sm content and increasing the quenching speed were favorable to forming the SmFe9 alloy,and SmFe9 alloy with a single phase could be prepared when the content of Sm was about 22.3 wt%and the quenching speed was above 51.84 m/s.In terms of element doping,compared with Co and V,Ti had a positive effect on improving the thermal stability of SmFe9 alloy.Its addition could reduce the decomposition of SmFe9 alloy at high temperatures and inhibit the precipitation of α-Fe.

关键词

SmFe9合金/元素掺杂/熔淬/热稳定性

Key words

TbCu7-type SmFe9 alloy/element doping/melt quenching method/thermal stability

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基金项目

国家自然科学基金项目(52101235)

浙江省科技厅重点研发项目(2021C01172)

浙江省基础公益研究项目(LGG22E010010)

出版年

2024
磁性材料及器件
中国西南应用磁学研究所

磁性材料及器件

影响因子:0.358
ISSN:1001-3830
参考文献量3
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