柴油机2024,Vol.46Issue(5) :8-16.DOI:10.12374/j.issn.1001-4357.2024.05.002

纳米颗粒强化船舶烟气CO2吸收解吸性能实验

Experiment of the Absorption and Desorption Performance of CO2 in Ship Flue Gas Enhanced by Nanoparticles

李倬毅 孟骏 郭姜敏 杨晓冬 马钢 刘少俊 郑成航
柴油机2024,Vol.46Issue(5) :8-16.DOI:10.12374/j.issn.1001-4357.2024.05.002

纳米颗粒强化船舶烟气CO2吸收解吸性能实验

Experiment of the Absorption and Desorption Performance of CO2 in Ship Flue Gas Enhanced by Nanoparticles

李倬毅 1孟骏 1郭姜敏 2杨晓冬 3马钢 3刘少俊 4郑成航2
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作者信息

  • 1. 浙江大学工程师学院,杭州 310015
  • 2. 浙江大学能源高效清洁利用全国重点实验室,杭州 310027
  • 3. 中国石油集团电能有限公司,大庆 163453
  • 4. 浙江大学工程师学院,杭州 310015;浙江大学能源高效清洁利用全国重点实验室,杭州 310027
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摘要

利用鼓泡吸收和解吸实验装置研究TiO2和SiO2纳米颗粒对质量分数为30%的单乙醇胺(monoethanolamine,MEA)溶液CO2吸收-解吸性能的影响.结果表明,质量分数为0.10%的TiO2-MEA吸收剂的吸收增强因子最佳,可以达到1.095.吸收前后纳米颗粒的粒径分布和Zeta电位基本保持不变,具有较好的稳定性.在解吸过程中,相较质量分数为30%的MEA吸收剂,质量分数为0.10%的TiO2-MEA和质量分数为0.10%的SiO2-MEA吸收剂相对热损耗分别降低7.1%和7.0%,解吸容量分别提升7.69%和7.53%.此外,纳米颗粒对其他有机胺吸收剂也具有一定作用,在解吸过程中,显著提高有机胺吸收剂解吸速率的峰值,缩短达到解吸速率峰值的时间,提高解吸效率.

Abstract

A bubbling absorption and desorption experimental device was used to study the effect of TiO2 and SiO2 nanoparticles on the CO2 absorption and desorption performance of MEA (monoethanolamine) absorbent with mass quality fraction of 30%. The results show that TiO2-MEA absorbent with mass fraction of 0.10% has the best absorption enhancement factor,which can reach 1.095. The particle size distribution and Zeta potential of the nanoparticles remain basically unchanged before and after absorption,indicating good stability. During the desorption process,compared with MEA absorbent with mass fraction of 30%,the relative heat duty of TiO2-MEA and SiO2-MEA absorbent both with mass fraction of 0.10% was reduced by 7.1% and 7.0% respectively,and the desorption capacity was increased by 7.69% and 7.53% respectively. In addition,nanoparticles also have a certain effect on other amine absorbents. During the desorption process,it significantly increases the peak value of the desorption rate of amine absorbent,shortens the time to reach the peak value of the desorption rate,and improves the desorption efficiency.

关键词

船舶柴油机/烟气/CO2捕集/纳米流体/传质增强

Key words

marine diesel engine/flue gas/CO2 capture/nanofluid/mass transfer enhancement

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基金项目

国家重点研发计划项目(2022YFE0208900)

出版年

2024
柴油机
中国船舶重工集团公司第七一一研究所

柴油机

影响因子:0.174
ISSN:1001-4357
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